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Studies of the formation, chemical reactivity, and properties of small clusters: Application to an understanding of aerosol formation and heterogeneous chemistry. Annual technical progress report, March 1989-March 1990.

机译：研究小团簇的形成，化学反应性和性质：应用于理解气溶胶形成和异质化学。年度技术进步报告，1989年3月至1990年3月。

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The small cluster program involves (1) studies of reactions related to formation and growth of heteromolecular clusters and their thermochemical properties, (2) studies of photoinitiated processes in clusters, (3) investigations related to heterogeneous reactions including the influence of reaction centers on the interconversion, and (4) theoretical calculations of properties, dynamics, and structure. A major thrust of the work during the past year has been devoted to a study of the role of ionization and the presence of ions on reactions and energetics. During the past few months, particular attention has been paid to systems having varying proton affinities. From the data, we can determine the influence of these values on the nature of the reactions and ascertain the ultimate chemical nature of the ionization center formed as a result of the reactions. 83 refs., 12 figs., 2 tabs.

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Castleman, A. W.;
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年度 1990
页码 1-68
总页数 68
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Acetone; Aerosols; Ammonia; Photochemical Reactions; Thermochemical Processes; Chemical Reaction Kinetics; Dissociation Energy; Energy Transfer; Ground States; Ions; Photolysis; Polyethylene Glycols; Progress Report; Resonance Ionization Mass Spectroscopy; Rydberg States; Solvation; Tunnel Effect; EDB/400201; EDB/360202; EDB/400500;

机译：丙酮;气溶胶;氨;光化学反应;热化学过程;化学反应动力学;解离能;能量转移;基态;离子;光解;聚乙二醇;进展报告;共振电离质谱;里德堡态;溶剂化;隧道效应; EDB / 400201; EDB / 360202; EDB / 400500;

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8. Studies of the formation, chemical reactivity, and properties of small clusters: Application to an understanding of aerosol formation and heterogeneous chemistry. Annual technical progress report, March 1989-March 1990 [R] . Castleman, A. W. 1990

机译：研究小团簇的形成，化学反应性和性质：应用于理解气溶胶形成和异质化学。年度技术进步报告，1989年3月至1990年3月

Studies of the formation, chemical reactivity, and properties of small clusters: Application to an understanding of aerosol formation and heterogeneous chemistry. Annual technical progress report, March 1989-March 1990.

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