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Preliminary Performance Estimates of Binary Geothermal Cycles Using Mixed-Halocarbon Working Fluids

机译：混合卤代烃工作流体对二元地热循环的初步性能评估

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The performance of Rankine cycle binary systems for power generation using a hydrothermal resource has been investigated as a part of the DOE/GTD Heat Cycle Research Program. To date mixtures of paraffin-type hydrocarbons and water-ammonia mixtures have been investigated. This report gives the first results of the consideration of mixtures of halocarbons as working fluids in these power cycles. The performance of mixtures of Refrigerant-114 (R-114) and Refrigerant-22 (R-22) in combinations from pure R-114 to pure R-22 was calculated for such cycles. Various alternatives were considered: (1) minimum geofluid outlet temperature constraint/no constraint, (2) dry turbine expansion/expansion through vapor dome, (3) use of a turbine exhaust gas recuperator/no recuperator. Results of the study indicate that the halocarbon mixtures are at least as good as the hydrocarbon mixtures previously analyzed for a 360 deg F resource. The magnitude of the net geofluid effectiveness (net energy produced per unit mass geofluid flow) for the R-114/R-22 mixtures is the same as for the best hydrocarbon mixtures previously analyzed. The percentage improvement in effectiveness in using mixtures over using the pure fluids as working fluids is comparable for both classes of working fluids. Recommendations are made to continue investigation of the halocarbon mixtures as possible alternatives to the hydrocarbon working fluids. (ERA citation 11:050376)

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