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Micro-Raman Spectroscopy of Fluid Inclusions in a Hopper Crystal in Halite

机译:Halite漏斗晶体中流体包裹体的微拉曼光谱

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Raman microscopy has been used successfully to analyze for dissolved sulfate in fluid inclusions in naturally occurring halite. Hopper crystals are crystals of halite (NaCl) whose structure is produced by crystal growth at the surface of a brine reservoir. Brine is trapped by defects in the growing crystal faces as microscopic fluid inclusions. In this study the hopper crystal was characterized by obtaining a profile of the sulfate (SO4 (2-) concentrations in brine inclusions in the bands formed in the hopper crystal structure. In addition, the same sample contained large areas of clear recrystallized halite in which fluid inclusions are not as abundant as those in hopper crystals but are several orders of magnitude larger (frequently several mm on an edge). These larger inclusions were also analyzed for their sulfate content. The sample for this study came from a thick halite unit in the Salado Formation (Permian age) in the Delaware Basin, southeastern New Mexico. The Waste Isolation Pilot Plant (WIPP) is located at a depth of approximately 2150 feet from the surface. (ERA citation 11:039012)

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