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Electrochemical and Kinetic Investigation of the Behavior of Gold in Chloride Solutions. III. The Gold(III)-Gold(I) Reaction on Platinum and the Disproportionation of Gold(I)

机译：氯化物溶液中金的电化学和动力学研究。 III。金（III） - 金（I）对铂的反应和金的歧化（I）

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Various electrochemical techniques were used in a study of the kinetics of the gold(III)-gold(I) couple on platinum in chloride solution, and of the initial stages of the deposition of gold on platinum. Differences in the behaviour of anodically treated platinum elelctrodes and gold electrodes were observed, and mechanisms are proposed for the reaction at both surfaces. The rate of homogeneous disproportionation of gold(I) in chloride solutions was found to be very slow, but it is catalysed at the surface of gold metal. The loss of gold as volatile species from a typical electrolyte at 50 exp 0 C has been shown to be negligible. 8 figures, 2 tables. (ERA citation 07:047383)

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Nicol, M. J.;
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年度 1981
页码 p.1-24
总页数 24
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Gold; Gold compounds; Electrodeposition; Valence; Oxidation; Reduction; Chemical reaction kinetics; Electrochemistry; Platinum; Electrodes; Chlorides; Electric currents; Electric potential;

机译：金;金化合物;电沉积;价;氧化;还原;化学反应动力学;电化学;铂;电极;氯化物;电流;电位;

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8. Electrochemical and Kinetic Investigation of the Behavior of Gold in Chloride Solutions. II. The Anodic Dissolution of Gold [R] . Nicol, M. J. 1981

机译：氯化物溶液中金的电化学和动力学研究。 II。金的阳极溶解

Electrochemical and Kinetic Investigation of the Behavior of Gold in Chloride Solutions. III. The Gold(III)-Gold(I) Reaction on Platinum and the Disproportionation of Gold(I)

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