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Silver-Silver Chloride Thermocells and Thermal Liquid Junction Potentials for Sodium Chloride Solutions at Elevated Temperatures

机译：高温下氯化钠溶液的银 - 氯化银热电池和热液接点电位

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Potentials for the thermocell (298.15 exp 0 K) Ag-AgCl/NaCl/AgCl-Ag(T exp 0 K) have been determined for NaCl concentrations ranging from 0.005 to 0.5 mol/Kg and for temperatures as high as 548.15 exp 0 K. Thermodynamic analysis of the cell has permitted evaluation of the initial state thermal liquid junction potentials ( delta phi/sub TLJP/) over the same range of conditions, and it was found that delta phi/sub TLJP/ increases in an approximately parabolic manner with delta T(=T-298.15 exp 0 K). The entropy of transport function t/sub +/S*/sub NA/sup +// - t /sub -/S*/sub Cl/sup -// has also been calculated. (ERA citation 09:012102)

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作者
Hwang, L. S.; Boateng, A.; Macdonald, D. D.;
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年度 1981
页码 1-12
总页数 12
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Thermal Batteries; Electric Potential; Entropy; Experimental Data; Silver; Silver Chlorides; Sodium Chlorides; Temperature Dependence;

机译：热电池;电势;熵;实验数据;银;氯化银;氯化钠;温度依赖性;

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8. Investigations of Selective Interactions of the Iron/Aqueous Sodium Chloride System. Part 1. The Adsorption of Chloride Ion by Alpha-Iron(III) Oxide in Sodium Chloride Solutions Saturated by Oxygen at 30C [R] . Kovacina, T. A., Venezky, D. L. 1971

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Silver-Silver Chloride Thermocells and Thermal Liquid Junction Potentials for Sodium Chloride Solutions at Elevated Temperatures

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