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Investigating Hydrogen Generation and Corrosion in the Treatment Tank and the Potential Formation of a Floating Layer in Neutralization Tank During Waste Tank Heel Chemical Cleaning

机译:在废水箱内部化学清洗过程中研究处理槽中的氢气产生和腐蚀以及中和槽中浮层的潜在形成

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The Savannah River Site (SRS) will remove sludge as part of waste tank closure operations. Typically the bulk sludge is removed by mixing it with water to create a slurry and transporting the slurry to a downstream tank for processing. Experience shows that a residual heel may remain that cannot be removed by this conventional technique. In the past, SRS used oxalic acid solutions to disperse or dissolve the sludge heel to complete the waste removal. To better understand the actual conditions of oxalic acid cleaning of carbon steel tanks, the authors developed and conducted an experimental program to determine its effectiveness in dissolving sludge, the hydrogen generation rate, the generation rate of other gases, the carbon steel corrosion rate, the impact of mixing on chemical cleaning, the impact of temperature, and the types of precipitates formed during the neutralization process.

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