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Reactions of n5-Cyclopentadienylcobalt(III) Alkyls with Cobalt(I) Phosphines and Iron Carbonyls, Evidence for Direct n5-Cyclopentadienyl and Trimethylphosphine Group Transfer Between Metal Centers.

机译：n5-环戊二烯基钴（III）烷基与钴（I）膦和羰基铁的反应，直接n5-环戊二烯基和三甲基膦基团在金属中心之间转移的证据。

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摘要

The mechanisms of reactions of organotransition metal complexes have only begun to be understood in detail during the last ten years. The complementary interaction of techniques and concepts developed earlier in studies of organic reaction mechanisms, with those commonly used in inorganic chemistry, has played a crucial role in helping to elucidate organormetallic reaction mechanisms. A few systems in which this interaction has proved especially fruitful are discussed in this article.

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作者
Bryndza, H. E.; Bergman, R. G.;
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年度 1980
页码 1-12
总页数 12
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Alkylnes; Cobalt; Phosphines; Iron; Carbonyls; Chemical reactions; Interactions; Metal complexes;

机译：烷基;钴;膦;铁;羰基化合物;化学反应;相互作用;金属配合物;

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1. The reactions of the monodentate organometallic phosphines [MI2(CO)(3){MeC(CH2PPh2)(3)-P,P '}] (M = Mo, W) with pi-allyl molybdenum(II) complexes and iron(O) and iron(II) carbonyl complexes [J] . Baker PK., Al-Jahdali M. Polyhedron: The International Journal for Inorganic and Organometallic Chemistry . 2002,第22期

机译：单齿有机金属膦[MI2（CO）（3）{MeC（CH2PPh2）（3）-P，P'}]（M = Mo，W）与π-烯丙基钼（II）配合物和铁（O）的反应）和羰基铁（II）配合物
2. Electron-transfer reactions of cobalt(III) complexes. 1. The kinetic investigation of the reduction of various surfactant cobalt(III) complexes by iron(II) in surface active ionic liquids [J] . Nagaraj Karuppiah, Murugan Krishnan Senthil, Thangamuniyandi Pilavadi, Spectrochimica acta, Part A. Molecular and biomolecular spectroscopy . 2015,第Null期

机译：钴（III）配合物的电子转移反应。 1.表面活性离子液体中铁（II）还原各种表面活性剂钴（III）配合物的动力学研究
3. Organometallic Lewis Acids, Part LVIIII [1]. Directed Synthesis of Dinuclear Metal Carbonyl Complexes of Rhenium, Iron, Chromium, and Tungsten with a Single Unsupported Halide or Pseudohalide Bridge (Cl-, Br-, I-, CN-, C(CN)(3)(-), NCS-, PPh2-, SH-) by Use of Re(CO)(5)FBF3 [J] . Fritz Peter M., Sacher Wolfgang, Beck Wolfgang Zeitschrift fur Naturforschung, B. A Journal of Chemical Sciences . 2014,第11a12期

机译：有机金属路易斯酸，第LVIIII部分[1]。 a，铁，铬和钨的双核金属羰基配合物的合成，含单个未支撑的卤化物或假卤化物桥（Cl-，Br-，I-，CN-，C（CN）（3）（-），NCS- ，PPh2-，SH-）通过使用Re（CO）（5）FBF3
4. Heteropolymetallic Complex Formation by the Reactions of Various Titanocene(III) Alkoxides with Metal Carbonyl Dimers [C] . Shota Ni1bavashi, Kaoru Mitsui, Kouki Matsubara, Symposium on Organometallic Chemistry . 2003

机译：通过金属羰基二聚体的各种二氧化钛（III）醇盐的反应的杂多金属复合物形成
5. Beyond alkyl transfer: Synthesis of main group metal (Mg, Ca, Zn) silyl and tris(oxazolinyl)borato complexes and their stoichiometric and catalytic reactions with borane Lewis acids and carbonyls. [D] . Lampland, Nicole Lynn. 2015

机译：超越烷基转移：合成主族金属（Mg，Ca，Zn）甲硅烷基和三（恶唑啉基）硼酸盐络合物，以及它们与硼烷路易斯酸和羰基化合物的化学计量和催化反应。
6. Mechanistic Studies on the Reaction between R2N-NONOates and Aquacobalamin: Evidence for Direct Transfer of a Nitroxyl Group from R2N-NONOates to Cobalt(III) Centers [O] . Hanaa A. Hassanin, Luciana Hannibal, Dr. Donald W. Jacobsen, -1

机译：R2N-NONO酸酯与水钴胺反应的机理研究：硝基氧从R2N-NONO酸酯直接转移至钴（III）中心的证据
7. Reaction of Coordinated Phosphines. V. Aryl and Alkyl Transfer from Tertiary Phosphine to Transition Metal [O] . Kiyoshi Kikukawa, Toru Yamane, Yoshihiro Ohbe, 1979

机译：配位膦的反应。 V.芳基和烷基转移从叔膦到过渡金属

Reactions of n5-Cyclopentadienylcobalt(III) Alkyls with Cobalt(I) Phosphines and Iron Carbonyls, Evidence for Direct n5-Cyclopentadienyl and Trimethylphosphine Group Transfer Between Metal Centers.

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