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Localized Corrosion Behavior of Type 304SS with a Silica Layer under Atmospheric Corrosion Environments

机译:大气腐蚀环境下304ss型二氧化硅层的局部腐蚀行为

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The U.S. Department of Energy (DOE) has proposed a potential repository for spent nuclear fuel and high-level radioactive waste at the Yucca Mountain site in Nevada. (I) The temperature could be high on the waste packages, and it is possible that dripping water or humidity could interact with rock dust particulate to form a thin electrolyte layer with concentrated ionic species. Under these conditions, it is possible that highly corrosion-resistant alloys (CRAs) used as packages to dispose the nuclear waste could suffer localized corrosion. Therefore, to better understand long-term corrosion performance of CRAs in the repository, it is important to investigate localized corrosion under a simulated repository environment. We measured open circuit potential (OCP) and galvanic current (i(sub g)) for silica-coated Type 304SS during drying of salt solutions under controlled RH environments to clarify the effect of silica layer as a dust layer simulant on localized corrosion under atmospheric environments. Type 304SS was used as a relatively susceptible model CRA instead of the much more corrosion resistant alloys, such as Alloy 22, that are being considered as, waste package materials.

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