INFRARED SPECTRA AND GEOMETRIES OF MATRIX ISOLATED YF3 AND YF2

机译：矩阵隔离YF3和YF2的红外光谱和几何

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The infrared spectra of YF3 and YF2 isolated in argon and nitrogen retraces have been measured in the region 40-800 cm-1. The fundamental frequency assignments in argon assuming C3v symmetry for YT3 are:V3(E), 663 cm"1;V2(A1), 119 cm-1;V4(E), 140 cm-1 with V1 unobserved. The frequency assignments for YF2 in nitrogen assuming C2v symmetry are V3 (B1), S38 cm-1;V1 (A1) 545 cm"1 and v2(A1), 134 cm-1. The results show that YF3 is easily reduced to YF2 in a tantalum Knudsen cell.

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R. D. Wesley; C. W. DeKock;
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年度 1972
页码 1-12
总页数 12
原文格式 PDF
正文语种 eng
中图分类工业技术;
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INFRARED SPECTRA AND GEOMETRIES OF MATRIX ISOLATED YF3 AND YF2

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