首页> 美国政府科技报告 >Development of regenerable copper-based sorbents for hot gas cleanup: Final technical report, September 1, 1995--August 31, 1996
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Development of regenerable copper-based sorbents for hot gas cleanup: Final technical report, September 1, 1995--August 31, 1996

机译:开发用于热气净化的可再生铜基吸附剂:最终技术报告,1995年9月1日 - 1996年8月31日

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The overall objective of this study was to determine the effectiveness of the copper-chromite sorbent (developed in previous ICCI-funded projects) for longer duration application under optimum conditions in the temperature range of 550(degrees)-650(degrees)C to minimize sorbent reduction and degradation during the cyclic process. Three (3) formulations of attrition resistant granules of the copper chromite sorbent (i.e., CuCr-10, CuCr-21, and CuCr-29) as well as one (1) copper chromite sorbent in pellet form (i.e., CuCr-36) were selected for cyclic desulfurization tests. The desulfurization and regeneration capabilities of the selected formulations as well as the effects of operating parameters were determined, to identify the (open quotes)best(close quotes) sorbent formulation and the optimum operating conditions. The durability of the (open quotes)best(close quotes) sorbent formulation was determined in (open quotes)long-term(close quotes) multicycle tests conducted at the optimum operating conditions. The attrition resistance of the selected formulations were determined and compared with those of other sorbents, including a limestone, a dolomite, and a commercial zinc titanate sorbent. The results obtained in this study indicate that, the CuCr-29 sorbent has excellent attrition resistance and desulfurization performance, which are far superior to the commercial zinc titanate sorbents. The optimum desulfurization temperature in terms of sorbent efficiency and utilization appears to be about 600(degrees)C. Sorbent regeneration at 750(degrees)C ensured complete conversion of the copper sulfide to oxide without sulfate formation or reactivity deterioration in subsequent cycles.

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