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首页> 美国政府科技报告 >Influence of surface defects and local structure on acid/base properties and oxidation pathways over metal oxide surfaces. Final report, June 1990-- January 1997
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Influence of surface defects and local structure on acid/base properties and oxidation pathways over metal oxide surfaces. Final report, June 1990-- January 1997

机译：表面缺陷和局部结构对金属氧化物表面酸/碱性质和氧化途径的影响。最后报告，1990年6月至1997年1月

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This final report covers work done during project period one and project period two. All the work in project period one was focused on the selective oxidation of oxygenated hydrocarbons over the SnO(sub 2)(110) single crystal surface. In project period two, the emphasis was on the acid/base properties of SnO(sub 2)(110) as well as two different Cu(sub 2)O single crystal surfaces. Prior to the summary of results, a description of these different surfaces is given as background information. Results are described for the dissociation and reaction of Bronsted acids (methanol, formic acid, water, formaldehyde, acetone, propene, acetic acid, and carbon monoxide). Results from project period two include: ammonia adsorption, CO(sub 2) adsorption, propene adsorption and oxidation, with tin oxides; complimentary work with copper oxides; and STM investigations.

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