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Reactivity of pi-Complexes of Ti, V, and Nb Towards Dithioacetic Acid: Synthesisand Structure of Novel Metal Sulfur-Containing Complexes

机译：Ti，V和Nbπ配合物对二硫代乙酸的反应性：新型金属含硫配合物的合成与结构

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In order to use sulfur-containing resources economically and with minimalenvironmental damage, it is important to understand the desulfurization processes. Hydrodesulfurization, for example, is carried out on the surface of a heterogeneous metal sulfide catalyst. Studies of simple, soluble inorganic systems provide information regarding the structure and reactivity of sulfur-containing compounds with metal complexes. Further, consistent with recent trends in materials chemistry, many model compounds warrant further study as catalyst precursors. The reactivity of low-valent organometallic sandwich pi-complexes toward dithiocarboxylic acids is described. For example, treatment of bisbenzene vanadium with CH3CSSH affords a divanadium tetrakis(dithioacetate) complex. The crystallographically determined V-V bond distance, 2.800(2), is nearly the same as the V-V bond distance in a V(mu-nu squared-S2)2V' unit in the mineral patonite (VS4)n. The stability of the V2S4 core in the dimer is demonstrated by evidence of V2S4(+) in the mass spectrum (70 eV, solid probe) of the vanadium dimer. Several other systems relevant to HDS catalysis are also discussed.

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Duraj, S. A.; Andras, M. T.; Hepp, A. F.;
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年度 1990
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总页数 6
原文格式 PDF
正文语种 eng
中图分类工业技术;
关键词
Catalysis; Desulfurizing; Metal surfaces; Niobium alloys; Reactivity; Sandwichstructures; Synthesis (Chemistry); Vanadium; Catalysts; Dimers; Heterogeneity; Mass spectra; Organometallic compounds; Sulfides;

机译：催化;脱硫;金属表面;铌合金;反应性;夹层结构;合成（化学）;钒;催化剂;二聚体;异质性;质谱;有机金属化合物;硫化物;

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机译：Ti，V和Nb的π配合物对二硫代乙酸的反应性：新型金属含硫配合物的合成和结构

Reactivity of pi-Complexes of Ti, V, and Nb Towards Dithioacetic Acid: Synthesisand Structure of Novel Metal Sulfur-Containing Complexes

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