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Scattering of Molecular Oxygen on Barium and Strontium Atoms in a Supersonic Molecular Beam Apparatus . Reaktive Streuung von O2 an BA-und Sr-Atomen in Einer Ueberschall-Molekularstrahlapparatur

机译：超声分子束装置中钡和锶原子上分子氧的散射。 Reiner streuung von O2 a Einer Ueberschall-molekularstrahlapparatur的Ba-und sr-atomen

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The activation energies and the scattering cross sections are determined for barium, using an oxygen hypersonic crossed molecular beam apparatus. The equipment consists of two vacuum chambers for the oxygen jet, a scattering chamber containing an oven for the thermal metal vapor jet, and a revolvable quadrupole mass spectrometer. The reactions Ba + O2 yields BaO + O and also Sr + O2 yields SrO + O are studied as reactive scattering processes, in which the relative collision energy can be increased to 1 eV. The activation energy for the formation of BaO is lower than 0.09 eV and the reactive scattering cross section for colliding end products in electronic ground state is 0.7 sq A for a collision energy of 0.3 eV and 0.4 sq A for 0.92 eV (error of approximately 50 %). The dissociation energy of SrO in 4.8 eV, and the reactive cross section is a factor of 10 larger than Ba + O2.

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Batalli-cosmovici, C.;
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年度 1972
页码 1-137
总页数 137
原文格式 PDF
正文语种 eng
中图分类工业技术;
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1. Effect of the molecular structure on the gas-surface scattering studied by supersonic molecular beam [J] . Kondo T, Kato HS, Yamada T, The European physical journal, D. Atomic, molecular, and optical physics . 2006,第1期

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2. Collisional orientation of the benzene molecular plane in supersonic seeded expansions, probed by infrared polarized laser absorption spectroscopy and by molecular beam scattering [J] . F.Pirani, M.Bartolomei, V.Aquilanti, The Journal of Chemical Physics . 2003,第1期

机译：超音速种子膨胀中苯分子平面的碰撞取向，通过红外偏振激光吸收光谱和分子束散射进行探测
3. Reinvestigation of the reaction of strontium and barium with iodobenzene and molecular structure of the heavy Grignard reagent [((thf)2BaPh2)4 o (thf)BaO] with an oxygen-centered square Ba5 pyramid [J] . Jens Langer, Martin Gartner, Reinald Fischer Inorganic Chemistry Communications . 2007,第9期

机译：锶和钡与碘苯的反应和重格氏试剂[（（thf）2BaPh2）4 o（thf）BaO]的分子结构与氧中心正方形Ba5金字塔的再研究
4. Study on Barium Strontium Titanate thin films integrated on Si substrates by laser Molecular Beam Epitaxy [C] . X.Y. Zhou, Y. Zhou, G. Y. Wang, International conference on multi-functional materials and structures . 2009

机译：激光分子束外延研究在硅衬底上集成钛酸锶钡钛薄膜
5. Growth of nanoscale barium titanate/strontium titanate superlattices by molecular-beam epitaxy [D] . Soukiassian, Arsen 2007

机译：分子束外延生长纳米级钛酸钡/钛酸锶超晶格
6. Crossed-molecular-beams reactive scattering of oxygen atoms [O] . R.J. Baseman 1982

机译：交叉分子束氧原子的反应散射
7. Crossed-Molecular-BEAMS Reactive Scattering of Oxygen Atoms [R] . Baseman, R. J. 1982

机译：交叉分子BEams氧原子的反应散射

Scattering of Molecular Oxygen on Barium and Strontium Atoms in a Supersonic Molecular Beam Apparatus . Reaktive Streuung von O2 an BA-und Sr-Atomen in Einer Ueberschall-Molekularstrahlapparatur

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