首页> 外文OA文献 >Crystal structures and thermal behaviour of lanthanide(III) hexanoate 1,10-phenanthroline complexes, M(C5H11CO2)(3)(phen) and Tm(C5H11CO2)(2)(NO3)(phen)

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Crystal structures and thermal behaviour of lanthanide(III) hexanoate 1,10-phenanthroline complexes, M(C5H11CO2)(3)(phen) and Tm(C5H11CO2)(2)(NO3)(phen)

机译：镧系元素己酸镧（III）1,10-菲咯啉配合物M（C5H11CO2）（3）（phen）和Tm（C5H11CO2）（2）（NO3）（phen）的晶体结构和热行为

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Lanthanide(III) hexanoate 1,10-phenanthroline complexes crystallise in the space group P2(1)/n. The compounds consist of dimers, whereby two lanthanide ions are held together by two bidentate bridging and two tridentate bridging carboxylate groups. The first coordination sphere of the lanthanide ions is completed by one bidentate chelating carboxylate group and by one bidentate 1,10-phenanthroline molecule, resulting in the coordination number 9. The dimers have a spherical form, which has important consequences for the thermal properties of complexes. The basic idea behind the preparation of this type of compounds is the stabilisation of the ionic lanthanide layer, so that the smaller lanthanide ions (from which the normal alkanoates do not show mesomorph-ism because they are too small) show liquid crystallinity. The stabilisation of the ionic layer was successful, expressed by the high melting temperatures, but mesomorphism is not observed. The absence of mesomorphism is related to the isotropic structure of the compounds. A lower symmetry is obtained when a hexanoate group is replaced by a nitrate group. Thulium(III) dihexanoate nitrate 1, 10-phenanthroline crystallises in the space group P (1) over bar. However, this compound also shows a spherical dimeric structure, but no mesomorphism.

机译：镧系元素（己酸）1,10-菲咯啉配合物在空间群P2（1）/ n中结晶。该化合物由二聚体组成，其中两个镧系元素离子通过两个双齿桥接和两个三齿桥接羧酸酯基团结合在一起。镧系元素离子的第一个配位球是由一个双齿螯合羧酸酯基团和一个双齿1,10-菲咯啉分子完成的，配位数为9。二聚体呈球形，这对氟的热性能产生重要影响。复合体。制备此类化合物的基本思想是稳定离子镧系元素层，从而使较小的镧系元素离子（正常的链烷酸酯因其太小而不能从中显示同构现象）表现出液晶性。离子层的稳定化是成功的，表现为高熔融温度，但未观察到介晶现象。介晶现象的缺乏与化合物的各向同性结构有关。当己酸酯基团被硝酸酯基团取代时，可获得较低的对称性。棒上的空间群P（1）中的硝酸己二酸三（（1）10-菲咯啉结晶。但是，该化合物也显示球形二聚体结构，但没有同构。

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Jongen Liesbet; Bromant Claudia; Hinz-Hübner Dirk; Meyer Gerd; Robeyns Koen; Van Hecke Kristof; Van Meervelt Luc; Binnemans Koen;
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年度 2003
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1. Crystal structures and thermal behaviour of lanthanide(III) hexanoate 1,10-phenanthroline complexes, [M(C5H11CO2)(3)(phen)] and [Tm(C5H11CO2)(2)(NO3)(phen)] [J] . Jongen L., Bromant C., Hinz-Hubner D., Zeitschrift fur Anorganische und Allgemeine Chemie . 2003,第6期

机译：镧系元素（III）己酸酯1,10-菲咯啉配合物[M（C5H11CO2）（3）（phen）]和[Tm（C5H11CO2）（2）（NO3）（phen）]的晶体结构和热行为
2. Synthesis and physical studies of lanthanide(III) complexes of N,N-bis(2-hydroxyethyl)glycinate (bicinate, bicH(2)(-)): molecular and crystal structure of [Gd(O2CMe)(bicH(2))(phen)(H2O)](ClO4) phen 3H(2)O (phen=1,10-phenanthroline) [J] . Messimeri A., Raptopoulou CP., Nastopoulos V., Inorganica Chimica Acta . 2002,第0期

机译：N，N-双（2-羟乙基）甘氨酸盐（bicinate，bicH（2）（-））镧系元素（III）配合物的合成和物理研究：[Gd（O2CMe）（bicH（2））的分子和晶体结构（phen）（H2O）]（ClO4）phen 3H（2）O（phen = 1,10-菲咯啉）
3. Reactions of 2,2'-bipyridine (bpy) and 1,10-phenanthroline (phen with yttrium(III) nitrate: preparation, X-ray crystal structures and spectroscopic characterization of the bis-bpy and bis-phen complexes [J] . Athanassios K.Boudalis, Vassilios Nastopoulos, Spyros P.Perlepes, Transition Metal Chemistry . 2001,第3期

机译：2,2'-联吡啶（bpy）和1,10-菲咯啉（phen与硝酸钇（III）的反应）：bis-bpy和bis-phen配合物的制备，X射线晶体结构和光谱表征
4. Hydrothermal Synthesis and Characterization of the Coordination Polymers with bta =Benzene-1,2,4,5- tetracarboxylate as Bridging Ligand: {Cu(phen)(μ4-bta)1/2· (H2O)}n(phen= 1,10-phenanthroline) [C] . International symposium on solid state chemistry in China amp; 8th Chinese national conference on solid state chemistry and inorganic synthesis : Book of abstracts . 2002

机译：以bta =苯-1,2,4,5-四羧酸苯酯为桥联配体的水热合成和表征：{Cu（phen）（μ4-bta）1/2·（H2O）} n（phen = 1,10-菲咯啉
5. Organometallic photonucleases. I. DNA cleavage by the photolysis of cyclopentadienyl metal complexes: Mechanistic studies and sequence selectivity of strand scission by CpW(CO)3CH3. II. Footprinting of chromatin structure and chromatin remodeling by SWI/SNF utilizing CpW(CO)3CH3. III. Dual mechanisms of DNA damage by MoX(eta3-allyl)(CO)3(phen) complexes. [D] . Downs, Jennifer. 2005

机译：有机金属光核酸酶。 I.通过环戊二烯基金属配合物的光解来切割DNA：通过CpW（CO）3CH3进行断裂的机理研究和序列选择性。二。 SWI / SNF利用CpW（CO）3CH3进行染色质结构足迹测定和染色质重塑。三， MoX（eta3-烯丙基）（CO）3（phen）复合物对DNA的双重破坏机制。
6. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of Mn(ph)(Phen)2(H2O)· 4H2O Mn(Phen)2(H2O)22(Isoph)2(Phen)· 12H2O and {Mn(Isoph)(bipy)4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 110-Phenanthroline; bipy = 22-Bipyridine) [O] . Michael Devereux, Malachy McCann, Vanessa Leon, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：Mn（ph）（Phen）2（H2O）·4H2OMn（Phen）2（H2O）2 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{Mn（Isoph）（bipy） 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 110-邻菲咯啉; bipy = 22 -联吡啶）
7. Synthesis and Biological Activity of Manganese (II) Complexes of Phthalic and Isophthalic Acid: X-Ray Crystal Structures of [Mn(ph)(Phen)2(H2O)]· 4H2O, [Mn(Phen)2(H2O)2]2(Isoph)2(Phen)· 12H2O and {[Mn(Isoph)(bipy)]4· 2.75biby}n(phH2 = Phthalic Acid; isoph = Isophthalic Acid; phen = 1,10-Phenanthroline; bipy = 2,2-Bipyridine) [O] . Devereux, Michael, McCann, Malachy, Leon, Vanessa, 2000

机译：邻苯二甲酸和间苯二甲酸锰（II）配合物的合成和生物活性：[Mn（ph）（Phen）2（H2O）]·4H2O，[Mn（Phen）2（H2O）2] 2的X射线晶体结构（Isoph）2（Phen）·12H2O和{[Mn（Isoph）（bipy）] 4·2.75biby} n（phH2 =邻苯二甲酸; isoph =间苯二甲酸; phen = 1,10-邻菲咯啉; bipy = 2,2 -联吡啶）

Crystal structures and thermal behaviour of lanthanide(III) hexanoate 1,10-phenanthroline complexes, M(C5H11CO2)(3)(phen) and Tm(C5H11CO2)(2)(NO3)(phen)

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