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Application of modified bentonite using sulfuric acid for the removal of hexavalent chromium from aqueous solutions

机译:硫酸改性膨润土在去除水溶液中六价铬中的应用

摘要

Background: Environmental contamination by chromium (Cr) has become an important issue due to its adverse effects on human health and environment. This study was done to evaluate the application of modified bentonite using sulfuric acid as an adsorbent in the removal of hexavalent Cr from aqueous solution.udMethods: Adsorbent features were determined using x-ray diffraction (XRD), fourier transformed infrared spectroscopy (FTIR) and scanning electron microscope (SEM) techniques. Thereafter, the effect of pH, contact time, adsorbent dosage and different concentrations of Cr was investigated. The experimental data was fitness in terms of kinetic and equilibrium adsorption processes.udResults: The maximum capacity (Qm) of Cr(VI) according to Langmuir model was obtained at 4.21 mg/g. The experimental data properly obeyed the Longmuir and pseudo-second-order models. The highest percentage of Cr(VI) adsorption was observed at pH = 3 and the process after 60 minutes reached the equilibrium state.udConclusion: In Langmuir expression, the dimensionless constant separation term (RL) values for the adsorption of Cr onto the modified bentonite was in the range of 0-1, indicating that the adsorption is a favorable process and the modified bentonite has good potential in removing hexavalent Cr using sulfuric acid.udKeywords: Modified bentonite, Sulfuric acid, Adsorption, Hexavalent chromium, Aqueous solution
机译:背景:铬(Cr)对环境的污染已对人类健康和环境造成不利影响,已成为一个重要问题。本研究旨在评估以硫酸为吸附剂的改性膨润土在去除水溶液中六价铬中的应用。 ud方法:使用X射线衍射(XRD),傅立叶变换红外光谱(FTIR)测定吸附剂的特性和扫描电子显微镜(SEM)技术。此后,研究了pH,接触时间,吸附剂量和不同浓度的Cr的影响。实验数据在动力学和平衡吸附过程方面具有适应性。 ud结果:根据Langmuir模型,Cr(VI)的最大容量(Qm)为4.21 mg / g。实验数据完全服从Longmuir模型和伪二阶模型。在pH = 3时观察到最高的Cr(VI)吸附率,并且60分钟后该过程达到平衡状态。 ud结论:在Langmuir表达式中,Cr在改性剂上的无量纲常数分离项(RL)值。膨润土在0-1范围内,表明吸附是一个有利的过程,改性膨润土具有很好的利用硫酸去除六价铬的潜力。 ud关键词:改性膨润土,硫酸,吸附,六价铬,水溶液

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