首页> 外文OA文献 >Assessment of Activity of 'Transparent and Clear' and 'Opaque and Highly Coloured' Photocatalytic Samples using a Fluorescent Photocatalytic Activity Indicator Ink, FPaii.
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Assessment of Activity of 'Transparent and Clear' and 'Opaque and Highly Coloured' Photocatalytic Samples using a Fluorescent Photocatalytic Activity Indicator Ink, FPaii.

机译:使用荧光光催化活性指示剂墨水FPaii评估“透明和透明”和“不透明和高度着色”光催化样品的活性。

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摘要

The photocatalytic activity of self-cleaning glass is assessed using a resazurin (Rz) photocatalyst activity indicator ink, i.e. Rz paii, via both the rate of change in the colour of the ink (blue to pink), R(Abs), and the rate of change in the fluorescence intensity, R(Fl), (λ(excitation) = 593 nm; λ(emission) = 639 nm) of the ink. In both cases the kinetics are zero order. Additional work with a range of glass samples of different photocatalytic activity reveal R(Abs) is directly related to R(Fl), thereby showing that the latter, like the former, can be used to provide a measure of the photocatalytic activity of the sample under test. The measured value of R(Fl) is found to be the same for 5 pieces of, otherwise identical, selfcleaning glass with: black, red, blue, yellow and no coloured tape stuck to their backs, which demonstrates that R(Fl) measurements can be used to measure photocatalytic activity under conditions of high colour and opacity under which R(Abs) cannot be measured. The relevance of this novel, fluorescence-based paii to the assessment of the activity of highly coloured, opaque photocatalytic samples, such as paints and tiles, is discussed briefly.
机译:使用刃天青(Rz)光催化剂活性指示剂墨水(即Rz paii)通过墨水颜色(蓝色至粉红色),R(Abs)和颜色变化率评估自清洁玻璃的光催化活性。油墨的荧光强度变化率R(F1)(λ(激发)= 593 nm;λ(发射)= 639 nm)。在两种情况下,动力学均为零级。对一系列具有不同光催化活性的玻璃样品的进一步研究表明,R(Abs)与R(F1)直接相关,从而表明后者(与前者一样)可用于测量样品的光催化活性。在测试中。发现R(F1)的测量值与5块相同的玻璃相同,否则相同,自清洁玻璃的颜色为:黑色,红色,蓝色,黄色,并且其背面没有粘贴彩色胶带,这表明R(F1)的测量结果可用于在无法测量R(Abs)的高颜色和不透明条件下测量光催化活性。简要讨论了这种新颖的基于荧光的涂料与高度着色,不透明的光催化样品(例如油漆和瓷砖)的活性评估之间的相关性。

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