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Study of the piezoresistivity of doped nanocrystalline silicon thin films

机译:掺杂纳米晶硅薄膜的压阻研究

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摘要

The piezoresistive response of n- and p-type hydrogenated nanocrystalline silicon thin films, deposited by hot-wire (HW) and plasma-enhanced chemical vapor deposition (PECVD) on thermally oxidized silicon wafers, has been studied using four-point bending tests. The piezoresistive gauge factor (GF) was measured on patterned thin-film micro-resistors rotated by an angle θ with respect to the principal strain axis. Both longitudinal (GFL) and transverse (GFT) GFs, corresponding to θ = 0° and 90°, respectively, are negative for n-type and positive for p-type films. For other values of θ (30°, 45°, 120°, and 135°) GFs have the same signal as GFL and GFT and their value is proportional to the normal strain associated with planes rotated by θ relative to the principal strain axis. It is concluded that the films are isotropic in the growth plane since the GF values follow a Mohr’s circle with the principal axes coinciding with those of the strain tensor. The strongest p-type pirezoresistive response (GFL = 41.0, GFT = 2.84) was found in a film deposited by PECVD at a substrate temperature of 250 °C and working pressure of 0.250 Torr, with dark conductivity 1.6 Ω−1cm−1. The strongest n-type response (GFL =− 28.1, GFT =− 5.60) was found in a film deposited by PECVD at 150 °C and working pressure of 3 Torr, with dark conductivity 9.7 Ω−1cm−1. A model for the piezoresistivity of nc-Si is proposed, based on a mean-field approximation for the conductivity of an ensemble of randomly oriented crystallites and neglecting grain boundary effects. The model is able to reproduce the measured GFL values for both n- and p-type films. It fails, however, to explain the transversal GFT data. Both experimental and theoretical data show that nanocrystalline silicon can have an isotropic piezoresistive effect of the order of 40% of the maximum response of crystalline silicon.
机译:通过四点弯曲试验研究了通过热线(HW)和等离子体增强化学气相沉积(PECVD)在热氧化硅晶片上沉积的n型和p型氢化纳米晶硅薄膜的压阻响应。在相对于主应变轴旋转了角度θ的图案化薄膜微电阻器上测量了压阻应变系数(GF)。纵向(GFL)和横向(GFT)GFs分别对应于θ= 0°和90°,对于n型薄膜为负,对于p型薄膜为正。对于其他θ值(30°,45°,120°和135°),GFs具有与GFL和GFT相同的信号,并且它们的值与与相对于主应变轴旋转θ的平面相关的法向应变成比例。可以得出结论,由于GF值遵循莫尔圆,主轴与应变张量的轴线重合,因此薄膜在生长平面上是各向同性的。在250°C的基板温度和0.250 Torr的工作压力下,通过PECVD沉积的薄膜中发现最强的p型抗压电响应(GFL = 41.0,GFT = 2.84),暗电导率为1.6Ω-1cm-1。在150°C和3 Torr的工作压力下,通过PECVD沉积的薄膜中发现了最强的n型响应(GFL = -28.1,GFT = -5.60),暗电导率为9.7Ω-1cm-1。基于随机取向微晶的电导率的平均场近似和忽略晶界效应,提出了nc-Si压阻模型。该模型能够再现n型和p型胶片的测量GFL值。但是,它无法解释横向GFT数据。实验和理论数据均表明,纳米晶硅可以具有大约为晶硅最大响应的40%的各向同性压阻效应。

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