首页> 外文OA文献 >Ligand C-C bond cleavage on ruthenium : observation of a reversible ruthenium(V)-imido/ruthenium(II)-amine couple and X-ray crystal structure of ru(bpy)2(NH=CMe2)2(PF6) 2 (bpy = 2,2′-bipyridine)

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Ligand C-C bond cleavage on ruthenium : observation of a reversible ruthenium(V)-imido/ruthenium(II)-amine couple and X-ray crystal structure of ru(bpy)2(NH=CMe2)2(PF6) 2 (bpy = 2,2′-bipyridine)

机译：配体CC键在钌上的裂解：可逆钌（V）-亚氨基/钌（II）-胺对的观察和ru（bpy）2（NH = CMe2）2（PF6）2的X射线晶体结构bpy = 2,2'-联吡啶）

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A reversible three-proton three-electron couple has been observed for the electrochemical oxidation of cis-[Ru(bpy)2(L)]2+ (L = 2,3-dimethyl-2,3-diaminobutane) in aqueous acidic solution; controlled-potential electrochemical oxidation of cis-[Ru(bpy)2(L)]2+ led to C-C bond cleavage in L and formation of cis-[Ru(bpy)2(NH=CMe 2)2]2+ whose structure has been determined by X-ray crystallography.

机译：观察到可逆的三质子三电子对在酸性水溶液中对顺式[Ru（bpy）2（L）] 2+（L = 2,3-二甲基-2,3-二氨基丁烷）的电化学氧化; -[Ru（bpy）2（L）] 2+的受控电势电化学氧化导致L中的CC键断裂并形成顺式[Ru（bpy）2（NH = CMe 2）2] 2+已经通过X射线晶体学确定。

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Wong KY; Che CM; Li CK; Chiu WH; Zhou ZY; Mak TCW;
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年度 1992
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6. Ligand C-C bond cleavage on ruthenium: Observation of a reversible ruthenium(V)-imido/ruthenium(II)-amine couple and X-ray crystal structure of ru(bpy)2(NH=CMe2)2(PF6) 2 (bpy = 2,2′-bipyridine) [O] . Wong KY, Che CM, Li CK, 1992

机译：在钌上的配体CC键裂解：观察可逆的钌（V） - 亚氨基/钌（II） - 胺偶和ru（bpy）2（NH = Cme2）2（pF6）2的X射线晶体结构（ bpy = 2,2'-联吡啶）

Ligand C-C bond cleavage on ruthenium : observation of a reversible ruthenium(V)-imido/ruthenium(II)-amine couple and X-ray crystal structure of ru(bpy)2(NH=CMe2)2(PF6) 2 (bpy = 2,2′-bipyridine)

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