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ZSM-35 MOLECULAR SIEVE AND PREPARATION METHOD THEREOF

机译:ZSM-35分子筛及其制备方法

摘要

The present application provides a ZSM-35 molecular sieve and a preparation method thereof. The ZSM-35 molecular sieve is an aggregated ZSM-35 molecular sieve having a hierarchical macro-meso-microporous pore structure. Raw materials for the preparation method do not include an organic template agent and a crystal seed, and the preparation method includes the following steps: preparing a reactant gel where a molar ratio of SiO2, Al2O3, Na2O, K2O, oxygen-containing acid radical and H2O is (20-40):1.0:(1.5-2.0):(4.0-6.5):(1.0-4.0):(600-1200); sequentially performing an aging treatment and a crystallization treatment on the reactant gel, washing and drying a resulting synthetic product. The ZSM-35 molecular sieve provided by the present application may be obtained by synthesizing without using an organic template agent and crystal seed, and because it has a hierarchical pore structure, it is favorable for material diffusion and mass transfer.
机译:本申请提供了ZSM-35分子筛及其制备方法。 ZSM-35分子筛是具有分级的大中观-微孔结构的聚集的ZSM-35分子筛。该制备方法的原料不包括有机模板剂和晶种,该制备方法包括以下步骤:制备反应物凝胶,其中SiO 2 ,Al 的摩尔比为2 O 3 ,Na 2 O,K 2 O,含氧自由基和H 2 O是(20-40):1.0:(1.5-2.0):( 4.0-6.5):( 1.0-4.0):( 600-1200);依次对反应物凝胶进行时效处理和结晶处理,洗涤并干燥所得合成产物。本申请提供的ZSM-35分子筛可以通过合成而无需使用有机模板剂和晶种而获得,并且由于其具有分级的孔结构,因此有利于材料扩散和传质。

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