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Nonionic Gemini surfactant of (Octylphenol polyoxyethylene ether disubstituted) dicarboxylic acid diphenyl ether and its synthesis method

机译:(辛基酚聚氧乙烯醚二取代)二羧酸二苯醚的非离子双子表面活性剂及其合成方法

摘要

The invention discloses a nonionic Gemini surfactant, (octylphenol polyoxyethylene ether disubstituted) dicarboxylic acid diphenyl ether and its synthesis method, which nonionic Gemini surfactant has a structural formula of:; embedded image ;and is prepared by a two-step reaction: S1, diphenyl ether 4,4′-dicarboxylic acid is subjected to an acyl chlorination reaction to obtain diphenyl ether 4,4′-dicarbonyl dichloride; S2, diphenyl ether 4,4′-dicarbonyl dichloride is subjected to an esterification reaction with octylphenol polyoxyethylene ether (OP-10) to obtain the target product (octylphenol polyoxyethylene ether disubstituted) dicarboxylic acid diphenyl ether. The surfactant of the present invention is expected to be applied in tertiary oil recovery as an alkali/surfactant, in polymer/surfactant binary composite flooding, in alkali/surfactant/polymer ternary composite flooding, as a microemulsion emulsifier and the like, and it can also be compounded with a common surfactant to reduce the use cost, and thus create conditions for its large-scale application.
机译:本发明公开了一种非离子型双子叶表面活性剂,结构式为:(辛基酚聚氧乙烯醚二取代)二羧酸二苯醚及其合成方法。 “嵌入式图像” ;和通过两步反应制备:S1,将二苯醚4,4′-二羧酸进行酰基氯化反应,得到二苯醚4,4′-二羰基二氯化物; S2中,使二苯醚4,4'-二羰基二氯化物与辛基酚聚氧乙烯醚(OP-10)进行酯化反应,得到目标产物(辛基苯酚聚氧乙烯醚二取代)二羧酸二苯醚。预期本发明的表面活性剂可作为碱/表面活性剂,聚合物/表面活性剂二元复合驱油,碱/表面活性剂/聚合物三元复合驱油,微乳液乳化剂等用于三次采油。还可以与普通表面活性剂混合使用,以降低使用成本,从而为其大规模应用创造条件。

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