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ELECTROCHEMICAL REDUCTIVE CARBOXYLATION OF UNSATURATED ORGANIC SUBSTRATES IN IONICALLY CONDUCTIVE MEDIUMS

机译:电导介质中不饱和有机基质的电化学还原羧化

摘要

The disclosure relates to methods for electrochemical reductive carboxylation of an unsaturated organic substrate to form a dicarboxylic organic product. The unsaturated organic substrate is electrochemically reduced with a carbon dioxide reactant in an ionically conductive, water-immiscible reactant medium to form the dicarboxylic organic product. The dicarboxylic organic product is recovered in an aqueous product medium. Example dicarboxylic organic products include phthalic acid, naphthalenedicarboxylic acid, furan-2,5-dicarboxylic acid, thiophene-2,5-dicarboxylic acid, pyrrole-2,5-dicarboxylic acid, adipic acid, suberic acid, sebacic acid, and 1,12-dodecanedioic acid.
机译:本公开涉及用于不饱和有机底物的电化学还原羧化以形成二羧酸有机产物的方法。在离子导电的,与水不混溶的反应介质中,用二氧化碳反应物将不饱和有机底物电化学还原,形成二羧酸有机产物。在含水产物介质中回收二羧酸有机产物。二羧酸有机产物的实例包括邻苯二甲酸,萘二甲酸,呋喃-2,5-二羧酸,噻吩-2,5-二羧酸,吡咯-2,5-二羧酸,己二酸,辛二酸,癸二酸和1, 12-十二烷二酸。

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