首页> 外国专利> METHOD FOR REAL-TIME MONITORING OF THE ELECTROLYTE CHARGE STATE OF THE REDOX FLOW BATTERY DURING OPERATION AND REDOX FLOW BATTERY CAPABLE OF MONITORING THE ELECTROLYTE CHARGE STATE IN REAL TIME DURING OPERATION

METHOD FOR REAL-TIME MONITORING OF THE ELECTROLYTE CHARGE STATE OF THE REDOX FLOW BATTERY DURING OPERATION AND REDOX FLOW BATTERY CAPABLE OF MONITORING THE ELECTROLYTE CHARGE STATE IN REAL TIME DURING OPERATION

机译:用于在操作期间对氧化还原流电池的电解质电荷状态进行实时监测的方法以及在操作期间可实时监测电解质充电状态的氧化还原流电池

摘要

The present invention relates to a method for monitoring electrolyte charging states of a redox flow battery in real time in-operation, and a redox flow battery capable of monitoring electrolyte charging states in real time in-operation, and more specifically, to a method which measures voltages of electrolytes and UV-vis absorbance, respectively, through a voltage measuring cell installed in pipes of a cathode electrolyte circulation unit and an anode electrolyte circulation unit and/or open circuit voltage measuring cells and UV-vis cells, and compares the same to monitor charging and discharging states of electrolytes in real time, and to a redox flow battery capable of monitoring electrolyte charging states in real time in-operation. The present invention measures the absorbance with a measuring solution (electrolyte itself) as a reference and provides convenience in maintenance. In addition, the present invention measures voltages and UV_vis absorbance of the electrolyte in real time without any loss of capacity of a redox flow battery and compares the same with a calibration curve, thereby being able to monitor charging and discharging states of the electrolyte in real time. Moreover, the present invention measures charging and discharging states of the electrolyte by crossing UV-vis cells along with the voltage measuring cells and OCV cells or simultaneously using the same such that the verification is doubly provided compared with existing technologies, thereby improving accuracy and stability.
机译:实时监测氧化还原液流电池的充电状态的方法技术领域本发明涉及一种实时监测氧化还原液流电池的充电状态的方法,以及一种能够实时监测氧化还原液流的电解液的方法,更具体地,涉及通过安装在阴极电解质循环单元和阳极电解质循环单元的管道中的电压测量单元和/或开路电压测量单元和UV-vis单元分别测量电解质的电压和UV-vis吸光度,并进行比较以实时监控电解质的充电和放电状态,并提供一种能够实时监控电解质充电状态的氧化还原液流电池。本发明以测量溶液(电解质本身)为基准来测量吸光度,并提供了维护上的便利。另外,本发明在不损失氧化还原液流电池的容量的情况下实时地测量电解质的电压和UV_vis吸收度,并将其与校准曲线进行比较,从而能够实时地监视电解质的充电和放电状态。时间。而且,本发明通过与电压测量电池和OCV电池一起穿过UV-vis电池或同时使用它们来测量电解质的充电和放电状态,从而与现有技术相比,双重地提供了验证,从而提高了准确性和稳定性。 。

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