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Coordination compounds having redox non-pure ligand and fluid battery containing the same
Coordination compounds having redox non-pure ligand and fluid battery containing the same
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机译:具有氧化还原非纯配体的配位化合物和包含该配位化合物的液体电池
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摘要
Electrolyte for flow batteries and other electrochemical systems may contain an active material capable of transferring a large number of electrons per oxidation-reduction cycle. Such an active material may comprise a coordination compound containing a metal center and at least one redox non-pure ligand. Thus, the flow battery may comprise a first half-cell having a first electrolyte therein, wherein the first electrolyte contains a coordination compound having at least one redox-non-pure ligand coordinated to the metal center. Certain redox non-pure ligands can comprise a quinone functional group, for example, a ligand having a catecholate having a quinone functional group. Some of the active materials may comprise a composition containing a coordination compound having at least one redox non-pure ligand coordinated to the metal center, wherein at least one redox non-pure ligand is a substituted catecholate having a quinone functionality group or Lt; / RTI
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