首页> 外国专利> METHOD FOR OBTAINING CONCENTRATED BRINE OF MINIMUM IMPURITY CONTENT FROM BRINE FOUND IN NATURAL SALT FLATS AND SALT MARSHES, SAID METHOD HAVING MINIMUM ENVIRONMENTAL IMPACT AND MAXIMUM LITHIUM RECOVERY

METHOD FOR OBTAINING CONCENTRATED BRINE OF MINIMUM IMPURITY CONTENT FROM BRINE FOUND IN NATURAL SALT FLATS AND SALT MARSHES, SAID METHOD HAVING MINIMUM ENVIRONMENTAL IMPACT AND MAXIMUM LITHIUM RECOVERY

机译:从天然盐味盐和盐沼中的盐分中获得最低杂质含量的浓缩盐的方法,该方法具有最小的环境影响和最大的锂回收率

摘要

The invention relates to a method for obtaining concentrated brine of minimum impurity content from brine found in natural salt flats and salt marshes, said method having minimum environmental impact and maximum lithium recovery. The method is characterised in that it comprises the steps of: a) constructing ponds for fractional crystallisation based on solar evaporation; b) filling the ponds with natural brine; c) initially pre-concentrating the natural brine until the maximum possible lithium concentration in the liquid phase is obtained, without lithium-containing salts being precipitated; d) cooling the pre-concentrated brine obtained in step (c), ensuring the maximum precipitation of salts containing sulphate anion; e) chemically pre-treating the liquid phase of the brine separated from the salts precipitated by means of cooling in order to minimise sulphate anions in the liquid phase after cooling; f) finally pre-concentrating the pre-treated liquid phase until the maximum possible lithium concentration in the liquid phase is obtained, without lithium-containing salts being precipitated; g) chemically treating the liquid phase of the brine separated from the salts precipitated in step (f) in order to minimise the concentration of magnesium, calcium, boron and sulphate in the liquid phase; and h) concentrating the liquid phase obtained in step (g).
机译:本发明涉及一种从天然盐滩和盐沼中发现的盐水中获得杂质含量最小的浓盐水的方法,该方法对环境的影响最小,而锂的回收率最大。该方法的特征在于其包括以下步骤:a)基于太阳蒸发来建造用于分级结晶的池; b)用天然盐水填充池塘; c)首先预浓缩天然盐水,直到在液相中获得最大可能的锂浓度,而没有沉淀出含锂盐; d)冷却步骤(c)中获得的预浓缩盐水,确保最大程度地沉淀含硫酸根阴离子的盐; e)对通过冷却从沉淀出的盐中分离出的盐水的液相进行化学预处理,以使冷却后液相中的硫酸根阴离子最小化; f)最后对浓缩的液相进行预浓缩,直至获得最大可能的液相锂浓度,而没有沉淀出含锂盐; g)化学处理从步骤(f)中沉淀的盐分离出的盐水的液相,以使液相中镁,钙,硼和硫酸盐的浓度最小化; h)浓缩步骤(g)中获得的液相。

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