首页> 外国专利> Molecularly imprinted polymer with inbuilt redox sampler and salt that provides counterions and the selective chemical sensor for electrochemical marking of selected analytes with a layer of the molecularly imprinted polymer as the recognizing unit

Molecularly imprinted polymer with inbuilt redox sampler and salt that provides counterions and the selective chemical sensor for electrochemical marking of selected analytes with a layer of the molecularly imprinted polymer as the recognizing unit

机译：具有内置氧化还原采样器和盐的分子印迹聚合物，该盐提供抗衡离子和选择性化学传感器，用于以分子印迹聚合物层作为识别单元对选定的分析物进行电化学标记

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摘要

The scope of the notification is a new monomer as a sample of redox consisting of p -[bis (2,2'-bitieno -5 -yl)methyl]-ferrocenebenzene and its production method, consisting of:that 4 -ferrocenebenzaldehyde as the parent compound is reacted with 2,2'-bitiophene in ethylene glycol in the presence of superchoric acid (VII),in the nitrogen atmosphere and at the temperature between -100 and 100 -c, preferably 60 -C, with the production of p -[bis (2,2'-bitieno -5 -yl)methyl]-ferrocenebenzene.In addition, the notification includes a molecular -printed polymer (MIP), in the form of a layer, as an entity recognising a selective chemotheraper for the electrochemical determination of the selected analysers,previously used as templates, in particular p -synephrine, with a built -in redox sample.The scope of the notification is also the way in which the molecular printed polymer (MIP) is produced and its application,in which the polymer (MIP) in question occurs as a layer as the unit of identification of the selected analyte, in particular p -synephrine,in a selective electrochemical detector and /or assay, both in synthetic and biological samples of human and animal origin,favourable in the absence of an external sample, redox in the test solution.

机译：通知的范围是一种新的作为氧化还原样品的单体，它由对-[双（2,2'-二叠氮基-5-基）甲基]二茂铁苯组成，其制备方法包括：以4-二茂铁苯甲醛为原料在超氯酸（VII）存在下，在氮气气氛中，在-100至100 -c，优选60 -C的温度下，使母体化合物与2,2'-联苯噻吩在乙二醇中反应，生成p -[双（2,2'-bitnono -5-基）甲基]-二茂铁苯。此外，该通知还包括一层分子形式的分子印刷聚合物（MIP），作为识别选择性化学疗法的实体。选定的分析仪的电化学测定，该分析仪以前用作模板，尤其是对-肾上腺素，具有内置的氧化还原样品。通报范围还包括分子印刷聚合物（MIP）的生产方法及其应用，其中所讨论的聚合物（MIP）以一层作为识别单位在人和动物来源的合成和生物学样品中，在选择性电化学检测器和/或测定法中对选定分析物，特别是对-正肾上腺素的分离，有利的是在没有外部样品的情况下，在测试溶液中进行氧化还原。

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公开/公告号PL422855A1

专利类型
公开/公告日2019-03-25

原文格式PDF
申请/专利权人 INSTYTUT CHEMII FIZYCZNEJ POLSKIEJ AKADEMII NAUK;
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申请/专利号PL20170422855
发明设计人 PATRYCJA ŁACH;MACIEJ CIEPLAK;MARTA SOSNOWSKA;PIYUSH S. SHARMA;RAGHU CHITTA;FRANCIS DSOUZA;WŁODZIMIERZ KUTNER;
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申请日2017-09-15
分类号C07D333/10;G01N33/50;
国家 PL
入库时间 2022-08-21 12:01:03

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