首页> 外国专利> New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, application of complex compounds of europium (III), new luminescent molecular probes for monitoring of polymerization processes, new luminescent molecular sensors for tests of coating materials

New photoinitiating systems for the processes of photoinitiated cationic, radical, thiol-ene and hybrid polymerization, new complex compounds of europium (III) and method for producing them, application of complex compounds of europium (III), new luminescent molecular probes for monitoring of polymerization processes, new luminescent molecular sensors for tests of coating materials

机译:用于光引发的阳离子,自由基,硫醇-烯和杂化聚合过程的新光引发体系,new的新络合物(III)及其制备方法,application的络合物的应用(III),用于监测氟的新型发光分子探针聚合工艺,用于涂层材料测试的新型发光分子传感器

摘要

the application relates to new systems fotoinicjujących to fotoinicjowanej cation polymerization processes, rodnikowej, tiol - en and hybrid, the new complex compounds europu (iii)and the method of their manufacture, uses complex compounds europu (iii)new luminescencyjnych molecular probes to monitor polymerization processes and new materials research luminescencyjnych molecular sensor for coating.new systems fotoinicjujące to fotoinicjowanej cation polymerization processes, rodnikowej, tiol - en and hybrid containing salts oniowe and ko - initiator, characterized by that,that contain (a) at least one salt selected from among the following: oniową jodoniowe salts selected from heksafluorofosforanu difenylojodoniowego, heksafluoroantymonianu difenylojodoniowego,heksafluorofosforanu 4 - methyl - 4 '- izopropylodifenylojodoniowego, heksafluorofosforanu 4,4' - dimetylodifenylo - jodoniowego,tetrakis pentafluorofenyloboranu 4 - methyl - 4 '- izopropylodifenylo - jodoniowego; salts sulfoniowe selected from heksafluorofosforanu trifenylo - sulfoniowego and heksafluoroantymonianu trifenylosulfoniowego; and (b) at least one selected from the group of ko - initiator complex compounds europu (iii) of general formula (1), in which: a1 means the grouping of general formula (2),in which the substituent r1 is chosen from among the following: group fenylowa, group 4 - fluorofenylowa, group 4 - chlorofenylowa, group 4 - metylofenylowa, group 4 - metoksyfenylowa, group 4 - cyjanofenylowa,group 4 - nitrofenylowa, group 2 - naftylowa, group 2 - tienylowa, group 2 - furylowa; a2 means grouping of general formula (3), in which the substituent r2 means hydrogen atom or methyl group.a2 means or grouping of the formula (4) or a2 means the grouping of formula (5) or a2 means the grouping of the formula (6).
机译:该应用涉及新的系统,从fotoinicjujących到fotoinicjowanej阳离子聚合过程,rodnikowej,tiol-en和hybrid,新的复合化合物europu(iii)及其制造方法,使用复合化合物europu(iii)新的发光探针监测聚合反应工艺和新材料研究用于涂层的分子发光传感器。从阳离子到阳离子的新系统,从阳离子到聚合反应工艺,罗德尼科维奇,tiol-en和含有盐的混合物oniowe和ko-引发剂,其特征在于,它们含有(a)至少一种选自以下的盐在以下之中:选自以下的盐:六氟氟膦酸酯二氟代邻苯二酚,六氟氟磺胺基壬酸酯,六氟氟磺胺基四甲基-甲基-4'-异丙基二氟噻吩基氟基翁可尔顿,六氟氟膦基四氟噻吩基4,4'-二甲基二氟苯基选自以下的盐磺基磺酸:三氟芴磺酸和三氟壬基磺酸壬基磺酸盐; (b)选自通式(1)的ko-引发剂配合物化合物europu(iii)的组中的至少一种,其中:a1是通式(2)的基团,其中取代基r1选自其中:fenylowa组,第4组-氟苯丙胺,第4组-氯芬尼洛华,第4组-甲烯基芬欧拉,第4组-甲氧西芬尼洛华,第4组-cyjanofenylowa,第4组-硝苯甲芬,第2组-naftylowa,第2组-tienylowa,第2组- furylowa a2表示通式(3)的基团,其中取代基r2表示氢原子或甲基。a2表示式(4)的基团或a2表示式(5)的基团或a2表示式(5)的基团(6)。

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