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Dendrite-Free Lithium Metal Battery by Deformation-Induced Potential Shielding

机译:无树突形锂金属电池的变形诱导电位屏蔽

摘要

Disclosed are a system and methods for preventing dendrite growth in an electrochemical cell through the use of a protective layer. The electrochemical cell may comprise an anode, a cathode, an electrolyte, and a protective layer, wherein the protective layer is capable of producing a voltage. The voltage produced can selectively shield metal ions from certain regions of the protective layer. This shielding can result in a more uniform flux of metal ions being transferred across the electrode-electrolyte interface in subsequent electrodeposition and electrodissolution processes. As a result, an electrode with such a protective layer can exhibit improved performance and durability, including markedly lower overpotentials and largely improved metal (e.g., lithium) retention.
机译:公开了通过使用保护层来防止电化学电池中的树枝状晶体生长的系统和方法。该电化学电池可以包括阳极,阴极,电解质和保护层,其中该保护层能够产生电压。产生的电压可以选择性地将金属离子与保护层的某些区域隔离开。这种屏蔽可以导致在随后的电沉积和电溶解过程中,更均匀的金属离子通量跨电极-电解质界面转移。结果,具有这种保护层的电极可以表现出改善的性能和耐久性,包括明显更低的过电势和大大改善的金属(例如锂)保持力。

著录项

  • 公开/公告号US2019165429A1

    专利类型

  • 公开/公告日2019-05-30

    原文格式PDF

  • 申请/专利权人 THE REGENTS OF THE UNIVERSITY OF MICHIGAN;

    申请/专利号US201816199441

  • 发明设计人 WEI LU;

    申请日2018-11-26

  • 分类号H01M10/42;H01M10/0585;H01M10/0525;

  • 国家 US

  • 入库时间 2022-08-21 12:06:44

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