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Silicone release coating composition and low release force emulsion silicone release coating for film and paper with cured release coating

机译:有机硅防粘涂料组合物和低固化力乳胶有机硅防粘涂料,用于具有固化防粘涂料的薄膜和纸张

摘要

This invention relates to a silicone release coating composition and a low release force emulsion silicone release coating for films and papers having cured release coating, providing a silicone release coating composition,comprising: (A) 100 weight parts of an organopolysiloxane fluid having a viscosity at 25℃ of 50 to 10,000 mPa·sand alkenyl content of 0.10 to 3.0wt%; (B) 0.5-40 weight parts of a diorganopolysiloxane represented by the average structural formula (1),having a viscosity at 25℃ of 5,000 to 150,000 mPa ·s and alkenyl content of 0.05 to 0.80 wt%: Rc 3SiO(RbRcSiO2/2)n1(Rc 2SiO2/2)n2SiRc 3 (1) wherein Rb is alkenyl having 2 to 8 carbon atoms; Rc is alkyl group having 1 to 8 carbon atoms or phenyl;n1 is a number that provides alkenyl content of 0.05 to 0.80 wt%;n2 is a number with a value of at least 1; and n1 + n2 is a number that provides this component with a viscosity at 25℃ of 5,000 to 150,000 mPa ·s; (C) an organohydrogenpolysiloxane that has a viscosity at 25℃ of 1 to 1,000 mPa ·s and that has at least two silicon-bonded hydrogen atoms in each molecule,and has alkyl group having 1 to 8 carbon atoms or phenyl group for its silicon-bonded organic groups, in an amount sufficient to provide a value of 0.8:1 to 5 :1 for the molar ratio of silicon- bonded hydrogen atoms in this organohydrogenpolysiloxane to the alkenyl groups in components (A) and (B); (D) a hydrosilylation reaction catalyst in a catalytic amount; (E) surfactant; (F) water; and (G) inhibitor.
机译:本发明涉及一种硅氧烷剥离涂料组合物和一种具有固化剥离涂料的用于薄膜和纸的低剥离力乳液硅氧烷剥离涂料,提供了一种硅氧烷剥离涂料组合物,其包含:(A)100重量份的粘度为100℃的有机聚硅氧烷流体。 25℃下50〜10,000mPa·s,链烯基含量为0.10〜3.0wt%; (B)0.5〜40重量份的平均结构式(1)表示的二有机聚硅氧烷,在25℃下的粘度为5,000〜150,000mPa·s,链烯基的含量为0.05〜0.80重量%:Rc 3SiO(RbRcSiO2 / 2) )n1(Rc 2SiO2 / 2)n2SiRc 3(1)其中Rb是具有2至8个碳原子的烯基; Rc为具有1至8个碳原子的烷基或苯基; n1为提供0.05至0.80wt%的烯基含量的数字; n2为值为至少1的数字; n1 + n2是使该成分在25℃时的粘度为5,000至150,000 mPa·s的数字; (C)在25℃下粘度为1至1,000mPa·s并且在每个分子中具有至少两个与硅键合的氢原子的有机硅聚硅氧烷,并且其硅具有具有1至8个碳原子的烷基或苯基-键合的有机基团,其量足以使该有机氢聚硅氧烷中的硅键合的氢原子与组分(A)和(B)中的烯基的摩尔比为0.8:1至5:1; (D)催化量的氢化硅烷化反应催化剂; (E)表面活性剂; (F)水; (G)抑制剂。

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