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Method for synthesizing 5,6-diaryl-2-pyrazyl triflate, triarylpyrazine derivative, and method for synthesizing organometallic complex

机译:5,6-二芳基-2-吡唑基三氟甲磺酸酯,三芳基吡嗪衍生物的合成方法以及有机金属配合物的合成方法

摘要

Provided is a 5,6-diaryl-2-pyrazyl triflate, its synthetic method, and a method for synthesizing an organometallic complex having a triarylpyrazine ligand from the 5,6-diaryl-2-pyrazyl triflate. The triflate is readily obtained from the corresponding 5,6-diarylpyrazin-2-ol, and the palladium-catalyzed coupling of the 5,6-diaryl-2-pyrazyl triflate with an arylboronic acid derivative leads to a high yield of a triarylpyrazine derivative having high purity. The use of the triarylpyrazine derivative in the reaction with a metal compound such as a metal chloride results in an ortho-metallated organometallic complex with high purity. The high purity of the organometallic complex contributes to the extremely high durability of a light-emitting element.
机译:提供了一种5,6-二芳基-2-吡唑基三氟甲磺酸酯,其合成方法以及由5,6-二芳基-2-吡唑基三氟甲磺酸酯合成具有三芳基吡嗪配体的有机金属配合物的方法。可以从相应的5,6-二芳基吡嗪-2-醇容易地获得三氟甲磺酸酯,并且钯催化的5,6-二芳基-2-吡唑基三氟甲磺酸酯与芳基硼酸衍生物的偶联导致高产率的三芳基吡嗪衍生物具有高纯度。在与金属化合物如金属氯化物的反应中使用三芳基吡嗪衍生物产生具有高纯度的邻金属化有机金属配合物。有机金属配合物的高纯度有助于发光元件的极高的耐久性。

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