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The method for preparing Polyester resin controllable a thermal property

机译:可控制热性能的聚酯树脂的制备方法

摘要

In order to improve workability and shrinkability in a post-process of a polyester resin, one or more modifying agents are used in the polyester resin to modify the molecular structure of the polyester to change its physical properties, The present invention relates to a polyester resin capable of controlling thermal properties and capable of imparting processability and processability, and a process for producing the polyester resin. The process for producing a polyester resin capable of controlling the thermal properties of the present invention comprises, as a main component, terephthalic acid and a diol, And is produced by a two-step polycondensation reaction under the condition of not more than 0.5 mol% of the metal catalyst and not more than 0.5 wt% of the heat stabilizer.The polyester resin capable of controlling the thermal characteristics of the present invention having the above-described structure and the method for producing the same can be prepared by using a conventional method, in which a compound material capable of changing the molecular structure of polyethylene terephthalate So that it can be uniformly dispersed during the reaction so as to form a curved molecular chain instead of a straight straight molecular chain in the molecular structure of the finally produced PET and consequently to slow down the crystallization rate so that Tg and Tc , And Tm. It also contains a compound with a weak molecular structure and can produce shrinkage at a certain temperature, so that the shrinking property and workability of the fiber can be adjusted in a desired direction at a post-processing temperature Let's do it.
机译:为了改善聚酯树脂的后加工中的可加工性和收缩性,在聚酯树脂中使用一种或多种改性剂以改性聚酯的分子结构以改变其物理性质。聚酯树脂能控制热性能并能赋予加工性和加工性的方法,以及制备聚酯树脂的方法。本发明的能够控制热特性的聚酯树脂的制造方法以对苯二甲酸和二醇为主要成分,在不超过0.5摩尔%的条件下通过两步缩聚反应来制造。可以通过常规方法制备具有上述结构的本发明的能够控制热特性的聚酯树脂及其制备方法,该聚酯树脂的含量为金属催化剂的0.5wt%,并且不超过热稳定剂的0.5wt%。 ,其中一种复合材料能够改变聚对苯二甲酸乙二醇酯的分子结构,从而使其在反应过程中均匀分散,从而在最终生产的PET的分子结构中形成弯曲的分子链,而不是笔直的分子链。因此减慢了结晶速度,使Tg和Tc以及Tm。它还包含分子结构较弱的化合物,并且在一定温度下会产生收缩,因此可以在后处理温度下沿所需方向调整纤维的收缩性和可加工性。

著录项

  • 公开/公告号KR101912676B1

    专利类型

  • 公开/公告日2018-10-29

    原文格式PDF

  • 申请/专利权人 도레이첨단소재 주식회사;

    申请/专利号KR20120115309

  • 发明设计人 조중연;윤용만;이규정;

    申请日2012-10-17

  • 分类号C08G63/183;C08G63/78;C08L67/03;

  • 国家 KR

  • 入库时间 2022-08-21 12:36:56

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