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Direct synthesis of CU-CHA by combination of CU complex and tetraethylammonium and its application to catalyst

机译：CU配合物与四乙铵结合直接合成CU-CHA及其在催化剂中的应用

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摘要

The present invention relates to a method for direct synthesis of a material having a CHA zeolite structure in the form of an aluminosilicate containing copper atoms, which comprises at least the following steps: (i) at least one water source, one copper source, one polyamine, one source of the Y 4 source element, one source of the X 3 source element, a tetraethylammonium cation as the sole OSDA and an alkali or alkaline earth source A ) / RTI cations, wherein the synthesis mixture has the following molar composition: _{_{YO 2: a X 2 O 3}} : b OSDA: c A: d H 2 O: e Cu: f polyamine (ii) crystallizing the mixture obtained in (i) in the reactor; (iii) recovering the crystalline material obtained in (ii).

机译：本发明涉及一种直接合成具有CHA沸石结构的含铜原子的硅铝酸盐形式的材料的方法，该方法至少包括以下步骤：（i）至少一个水源，一个铜源，一个多胺，Y 4源元素的一种来源，X 3源元素的一种来源，作为唯一OSDA的四乙基铵阳离子和碱金属或碱土金属A）阳离子，其中合成混合物具有以下摩尔数组成：_{_{YO 2：a X 2 O 3 ：b OSDA：c A：d H 2 O：e Cu：f多胺（ii ）在反应器中使（i）中获得的混合物结晶; （iii）回收在（ii）中获得的结晶材料。}} 展开▼

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公开/公告号KR20180023890A

专利类型

公开/公告日2018-03-07

原文格式PDF

申请/专利权人 콘세호 수페리오르 데 인베스티가시오네스 시엔티피카스 씨.에스.아이.씨.;우니베르시타뜨 뽈리떼끄니까 데 발렌시아;
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申请/专利号KR20177033090

发明设计人 코르마 까노스 아벨리노;몰리네르 마린 마누엘;마르틴 가르시아 누리아;
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申请日2016-05-03

分类号C01B39/48;B01D53/94;B01J29/74;B01J29/76;C01B21/02;C07C29/94;C07C31/04;

国家 KR

入库时间 2022-08-21 12:40:39

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中文文献

1. 通过组合Cu络合物和四乙基铵直接合成Cu-CHA及其在催化中的应用 [P] . 中国专利： CN107750232B . 2021.02.12

2. 以四乙基氢氧化铵与铜氨络合物混合作为模板剂一步合成Cu-CHA催化剂的方法 [P] . 中国专利： CN105251528A . 2016-01-20

3. DIRECT SYNTHESIS OF CU-CHA BY MEANS OF COMBINING A CU COMPLEX AND TETRAETHYLAMMONIUM AND APPLICATIONS IN CATALYSIS [P] . ZA201707109B . 2020-01-29

机译：铜配合物与四乙铵联用法直接合成铜-CHA及其在催化中的应用

4. Direct synthesis of Cu-CHA by means of combining a Cu complex and tetraethylammonium and applications in catalysis [P] . 美国专利： US10676367B2 . 2020.06.09

5. direct synthesis of cu-cha by combining a cu-tetraethylammonium complex and catalysis applications. [P] . BR112017023663A2 . 2018-07-17

机译：通过将Cu-四乙基铵络合物与催化应用相结合，可直接合成cu-cha。

1. Highly effective direct synthesis of DMC from CH3OH and CO2 using novel Cu-Ni/C bimetallic composite catalysts [J] . Jun Bian, Min Xiao, Shuan Jin Wang, 中国化学快报（英文版） . 2009,第003期

2. High Activity and Selectivity of Cu/SiO2 Catalyst for the Direct Synthesis of Indole [J] . 中国化学快报（英文版） . 2002,第003期

3. Composition-driven Cu-speciation and reducibility in Cu-CHA zeolite catalysts: a multivariate XAS/FTIR approach to complexity [J] . Martini A., Borfecchia E., Lomachenko K. A., Chemical science . 2017,第10期

4. Mechanistic Understanding of Cu-CHA Catalyst as Sensor for Direct NH3-SCR Monitoring: The Role of Cu Mobility [J] . Chen Peirong, Rizzotto Valentina, Khetan Abhishek, ACS applied materials & interfaces . 2019,第8期

5. Understanding the structure directing action of copper-polyamine complexes in the direct synthesis of Cu-SAPO-34 and Cu-SAPO-18 catalysts for the selective catalytic reduction of NO with NH3 [J] . Turrina Alessandro, Eschenroeder Eike C. V., Bode Bela E., Microporous and mesoporous materials: The offical journal of the International Zeolite Association . 2015,第Null期

6. Complex Catalysts for Direct Synthesis of Dimethyl Ether From Synthesis Gas. Part II. The Interaction of the Process Reactants and Products with the Catalyst Surfaces [C] . Natalia I. Kosova, Irina A. Kurzina, Larisa N. Kurina Russian-German Forum on Nanotechnology . 2014

7. I. Multicatalysis: Development of a Bismuth(III) triflate-catalyzed Nucleophilic addition/ Hydrofunctionalization Reaction in the Synthesis of Complex Heterocycles II. C--H Arylation of Arenes and Heteroarenes with Palladium-Carboxylate Catalysts: Identification of the Catalyst Resting State and the Crucial Role of Pivalate Ligand in Stabilization of the Catalyst III. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Importance of Phosphine Ligand for Basic Heteroarene Substrates IV. C--H Arylation of Heteroarenes with Palladium-Carboxylate Catalysts: Effect of the Properties of Basic Heteroarene Substrates on Direct Arylations. [D] . Tundel, Rachel E. 2011

8. Composition-driven Cu-speciation and reducibility in Cu-CHA zeolite catalysts: a multivariate XAS/FTIR approach to complexity [O] . A. Martini, E. Borfecchia, K. A. Lomachenko, 2018

9. Understanding the structure directing action of copper-polyamine complexes in the direct synthesis of Cu-SAPO-34 and Cu-SAPO-18 catalysts for the selective catalytic reduction of NO with NH3 [O] . Turrina, Alessandro, Eschenroeder, Eike Christian Viktor, Bode, Bela Ernest, 2015

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2. Synthesis and applications of mesoporous Cu-Zn-Al_2O_3 catalyst for dehydrogenation of 2-butanol [J] . Deren Fang ,Wanzhong Ren ,Zhongmin Liu . 天然气化学杂志：英文版 . 2009,第2期

3. Enhanced catalytic performance for direct synthesis of dimethyl ether from syngas over a La_2O_3 modified Cu-ZrO_2/γ-Al_2O_3 hybrid catalyst [J] . Zhuo Li ,Jianqing Li ,Cheng Yang . 天然气化学杂志：英文版 . 2012,第3期

4. Pd-Ag膜催化剂的制备及在直接合成H_2O_2中的应用 [C] . 鲍世国 ,崔萌 ,刘国柱 . 中国无机盐工业协会过氧化物分会2007年行业会议 . 2007

5. 磁性纳米粒子或介孔MCM-41负载金配合物催化剂的合成及其在有机合成中的应用研究 [A] . 杨为森 . 2017