首页> 外国专利> CATALYTIC MATERIAL FOR CATALYTICALLY ACTIVATING PERSULFATE AND DEGRADING TYPICAL POLLUTANTS IN PAPERMAKING WASTEWATER IN TARGETED MODE, AND SYNTHETIC METHOD THEREFOR AND APPLICATION THEREOF

CATALYTIC MATERIAL FOR CATALYTICALLY ACTIVATING PERSULFATE AND DEGRADING TYPICAL POLLUTANTS IN PAPERMAKING WASTEWATER IN TARGETED MODE, AND SYNTHETIC METHOD THEREFOR AND APPLICATION THEREOF

机译:有针对性的催化造纸废水中过硫酸盐降解典型污染物的催化材料及其合成方法及其应用

摘要

A catalytic material for catalytically activating persulfate and degrading typical pollutants in papermaking wastewater in a targeted mode, and a synthetic method therefor and an application thereof. By using MIL-88A as a precursor, preparing MIL-88A@MIP using a molecular imprinting method, and using MIL-88A@MIP as a catalyst, and according to the characteristics that a metal organic framework is high in active site and high in catalytic activity, persulfate is catalytically activated at normal temperature to generate sulfate radical anions, and degradation-resistant pollutants, i.e., phthalate esters, in the papermaking wastewater are selectively degraded. The catalyst is easy to recycle and can be recycled multiple times. The method is appropriate for treatment of various kinds of organic wastewater, especially has a good effect on removing the degradation-resistant pollutants, i.e., phthalate esters, in the papermaking wastewater.
机译:以目标方式催化活化硫酸盐并降解造纸废水中典型污染物的催化剂材料及其合成方法和应用。以MIL-88A为前驱体,采用分子印迹法制备MIL-88A @ MIP,并以MIL-88A @ MIP为催化剂,并根据金属有机骨架的活性部位高,活性高等特点进行制备由于具有催化活性,过硫酸盐在常温下被催化活化以生成硫酸根自由基阴离子,并选择性降解造纸废水中的抗降解污染物,即邻苯二甲酸酯。该催化剂易于回收并且可以多次回收。该方法适用于各种有机废水的处理,尤其对去除造纸废水中的抗降解污染物邻苯二甲酸酯有很好的效果。

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