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Electrodeposition of platinum/iridium (Pt/Ir) on Pt microelectrodes with improved charge injection properties

机译:在铂微电极上电沉积铂/铱(Pt / Ir),具有改善的电荷注入性能

摘要

Aspects of the present disclosure are directed to electrochemical approaches for synthesis of platinum-iridium alloys with selected platinum-iridium ratio content and subsequently predetermined mechanical properties and electrochemical impedance properties. Such can provide a simple and cost-effective process for preparing these electrodes, as compared to conventional thin film processing techniques. A three-electrode electrochemical electrodeposition system is described including an electrochemical cell with a working electrode on which the electrodeposited film is deposited, a counter electrode to complete the electrochemical circuit and a reference electrode to measure and control surface potential. Mixed layers of platinum atoms and iridium atoms can be deposited from electrolyte solution onto the working electrode surface to create an electrically conductive surface with material properties related to the composition of the as-deposited film. The mechanical properties and electrochemical properties of the film can be tuned by adjusting the electrodeposition parameters.
机译:本公开的方面针对用于合成具有选定的铂-铱比率含量并随后具有预定的机械性能和电化学阻抗性能的铂-铱合金的电化学方法。与常规的薄膜处理技术相比,这可以提供用于制备这些电极的简单且成本有效的方法。描述了一种三电极电化学电沉积系统,其包括具有工作电极的电化学电池,在该工作电极上沉积有电沉积膜,用于完成电化学电路的对电极以及用于测量和控制表面电势的参考电极。可以将铂原子和铱原子的混合层从电解质溶液中沉积到工作电极表面上,以创建具有与所沉积的膜的成分有关的材料特性的导电表面。膜的机械性能和电化学性能可以通过调节电沉积参数来调节。

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