首页> 外国专利> New papermaking process by applying a base copolymer that has reacted with an aldehyde as a dry strength, retention, tear and machinability agent

New papermaking process by applying a base copolymer that has reacted with an aldehyde as a dry strength, retention, tear and machinability agent

机译:通过应用已与醛反应作为干强度,保持力,撕裂性和可机加工性试剂的基础共聚物的新造纸工艺

摘要

Method of manufacturing a sheet of paper and / or cardboard and the like, according to which, before or after said sheet is formed, the cellulosic material is contacted with at least one additive, characterized in that said additive is a (co ) cationic or amphoteric polymer resulting from the reaction between at least one aldehyde and at least one (co) base polymer comprising at least one nonionic monomer selected from the group comprising acrylamide (and / or methacrylamide), N, N-dimethylacrylamide , and / or acrylonitrile, said base copolymer being previously modified with at least one polyfunctional compound comprising at least 3 heteroatoms selected from N, S, O, P, of which at least 3 of these heteroatoms each have at least one hydrogen mobile; the (co) base polymer being modified with at least one polyfunctional compound, either incorporating additional polyfunctional compound (s) before or during the polymerization of the constituent comonomers of the (co) base polymer, or by grafting of the additional polyfunctional compound (s) in the base (co) polymer; the polyfunctional compound (s) being selected from the group comprising polyethyleneimines (PEI), primary polyamines, secondary polyamines, polyallylamines, polythiols, polyols, epichlorohydrin polyamides (PAE), and polyamines amides (PAA); the aldehyde being selected from the group comprising glyoxal, glutaraldehyde, furan dialdehyde, 2-hydroxyadipaldehyde, succinaldehyde, dialdehyde starch, 2,2-dimethoxyethanal, diepoxy compounds, and combinations thereof.
机译:一种制造纸和/或纸板等的薄片的方法,根据该方法,在形成所述薄片之前或之后,使纤维素材料与至少一种添加剂接触,其特征在于,所述添加剂是(共)阳离子或至少一种醛与至少一种(共)基础聚合物之间的反应得到的两性聚合物,所述基础聚合物包含至少一种选自丙烯酰胺(和/或甲基丙烯酰胺),N,N-二甲基丙烯酰胺和/或丙烯腈的非离子单体,所述基础共聚物预先用至少一种包含至少三个选自N,S,O,P的杂原子的多官能化合物改性,其中这些杂原子中的至少3个各自具有至少一个氢移动性; (共)基础聚合物用至少一种多官能化合物改性,或者在(共)基础聚合物的组成共聚单体的聚合之前或期间掺入另外的多官能化合物,或者通过接枝另外的多官能化合物)在基础(共)聚合物中;多官能化合物选自聚乙烯亚胺(PEI),伯多胺,仲多胺,聚烯丙基胺,多硫醇,多元醇,表氯醇聚酰胺(PAE)和多胺酰胺(PAA);所述醛选自乙二醛,戊二醛,呋喃二醛,2-羟基己二醛,丁二醛,二醛淀粉,2,2-二甲氧基乙醛,二环氧化合物及其组合。

著录项

  • 公开/公告号ES2609676T3

    专利类型

  • 公开/公告日2017-04-21

    原文格式PDF

  • 申请/专利权人 S.P.C.M. SA;

    申请/专利号ES20130712850T

  • 发明设计人 HUND RENÉ;BARRIERE CYRIL;

    申请日2013-02-26

  • 分类号D21H17/37;C08F8/28;D21H17/54;D21H21/10;D21H21/18;

  • 国家 ES

  • 入库时间 2022-08-21 13:35:24

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