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Non-noble metal based electro-catalyst compositions for proton exchange membrane based water electrolysis and methods of making

机译:用于基于质子交换膜的水电解的非贵金属基电催化剂组合物及其制备方法

摘要

The invention provides electro-catalyst compositions for an anode electrode of a proton exchange membrane-based water electrolysis system. The compositions include a noble metal component selected from the group consisting of iridium oxide, ruthenium oxide, rhenium oxide and mixtures thereof, and a non-noble metal component selected from the group consisting of tantalum oxide, tin oxide, niobium oxide, titanium oxide, tungsten oxide, molybdenum oxide, yttrium oxide, scandium oxide, cooper oxide, zirconium oxide, nickel oxide and mixtures thereof. Further, the non-noble metal component can include a dopant. The dopant can be at least one element selected from Groups III, V, VI and VII of the Periodic Table. The compositions can be prepared using a surfactant approach or a sol gel approach. Further, the compositions are prepared using noble metal and non-noble metal precursors. Furthermore, a thin film containing the compositions can be deposited onto a substrate to form the anode electrode.
机译:本发明提供了用于基于质子交换膜的水电解系统的阳极电极的电催化剂组合物。所述组合物包含选自由氧化铱,氧化钌,氧化rh及其混合物组成的组的贵金属组分,以及选自由氧化钽,氧化锡,氧化铌,氧化钛组成的组的非贵金属组分,氧化钨,氧化钼,氧化钇,氧化scan,氧化铜,氧化锆,氧化镍及其混合物。此外,非贵金属组分可以包括掺杂剂。掺杂剂可以是选自元素周期表的III,V,VI和VII族的至少一种元素。可以使用表面活性剂方法或溶胶凝胶方法来制备组合物。此外,使用贵金属和非贵金属前体制备组合物。此外,可以将包含所述组合物的薄膜沉积在基板上以形成阳极。

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