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Method for inhibiting self-absorption effect in laser-induced breakdown spectroscopy

机译:抑制激光诱导击穿光谱中自吸收效应的方法

摘要

Provided is a method for inhibiting self-absorption effect of a LIBS, comprising ablating a to-be-measured sample via a pulse laser thereby generating plasma, and selectively stimulating the plasma using a wavelength-tunable laser beam enabling transition of particles in a ground-state in the plasma to high energy state as stimulated absorption, thereby improving a stimulated absorption transition efficiency of the particles in a ground-state, and preventing plasma spectrum from being influenced by self-absorption effect. The invention is capable of eliminating the self-absorption effect without introducing external interference, obtaining original characteristics of emission spectrum from the center of the plasma, and essentially inhibiting and finally eliminating the self-absorption effect of laser plasma by making use of intrinsic physical property of plasma.
机译:提供了一种抑制LIBS的自吸收作用的方法,该方法包括:经由脉冲激光烧蚀待测样品,从而产生等离子体;以及使用波长可调激光束选择性地刺激等离子体,从而使粒子能够在地面上过渡。在等离子体中从激发态到激发态的高能态,从而提高了基态颗粒的激发态吸收跃迁效率,并防止了等离子体光谱受到自吸收效应的影响。本发明能够在不引入外部干扰的情况下消除自吸收效应,从等离子体中心获得发射光谱的原始特性,并利用固有的物理性质从本质上抑制并最终消除了激光等离子体的自吸收效应。血浆。

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