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LIQUID COATING COMPOSITIONS FOR USE IN METHODS FOR FORMING A SUPERHYDROPHOBIC, SUPEROLEOPHOBIC OR SUPERAMPHIPHOBIC LAYER

机译:液体涂料组合物,用于形成超疏水,超疏油或超疏油层的方法

摘要

The present invention provides for method for forming a superhydrophobic, superoleophobic or superamphiphobic layer and imparting said property on a surface, comprising the steps of: a. preparing a liquid coating composition comprising a solvent and dispersed silicone nanoparticles, b. optionally priming the surface to form a primed surface on which a superhydrophobic, superoleophobic or superamphiphobic layer is to be formed, c. applying a layer of the liquid coating composition on the surface or primed surface on which the superhydrophobic, superoleophobic or superamphiphobic layer is to be formed, d. evaporating the solvent from the liquid coating composition to form a superhydrophobic, superoleophobic or superamphiphobic layer and impart said property on the surface or primed surface, wherein the dispersed silicone nanoparticles are formed by polymerization of at least one compound of formula I in an aprotic solvent comprising 5 to 500 ppm of water, RaSi(R1)n(X1)3-n (I) wherein Ra is a straight-chain or branched C(1-24) alkyl or alkenyl group, an aromatic group which is linked by a single covalent bond or linked by a straight-chain or branched alkylene unit having 1 to 8 carbon atoms, to the Si-atom, R1 a straight chain or a branched hydrocarbon radical having 1 to 6 carbon atoms, X1 is a hydrolysable group, which is one or more of a halogen or an alkoxy group, and n is 0 or 1, and preferably is 0.
机译:本发明提供了形成超疏水,超疏油或超两疏层并在表面上赋予所述性质的方法,该方法包括以下步骤:a。制备包含溶剂和分散的硅氧烷纳米颗粒的液体涂料组合物,b。任选地底涂该表面以形成底涂的表面,在其上形成超疏水,超疏油或超两性的层,c。 d。在要形成超疏水,超疏油或超两性层的表面或打底的表面上涂一层液体涂料组合物,d。从液体涂料组合物中蒸发溶剂以形成超疏水,超疏油或超两疏层,并在表面或涂有底漆的表面上赋予所述性质,其中分散的有机硅纳米颗粒通过至少一种式I化合物在非质子溶剂中的聚合而形成。 5至500 ppm的水,RaSi(R1)n(X1)3-n(I),其中Ra是直链或支链C(1-24)烷基或烯基,是通过一个单键连接的芳族基团通过共价键或通过具有1至8个碳原子的直链或支链亚烷基单元连接至Si原子,R1为具有1-6个碳原子的直链或支链烃基,X1为可水解基团,卤素或烷氧基中的一个或多个,并且n为0或1,并且优选为0。

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