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ION SOURCE WITH PHOTOIONISATION AT ATMOSPHERIC PRESSURE

机译:大气中具有光化作用的离子源

摘要

FIELD: physics.;SUBSTANCE: ion source with photoionisation at atmospheric pressure is in the form of a hollow nitrogen gas stream which blows the heated outlet of a capillary chromatographic column and simultaneously functions as an ionisation chamber by separating an external background gas (laboratory air) from a carrier gas stream coming from the chromatographic column together with the ionised substance inside the hollow nitrogen gas stream. A source of ionising ultraviolet radiation is placed orthogonal to the gas stream. Ions formed along the axis of the gas stream, together with the stream, are transmitted to the input of an analyser interface. To prevent secondary ion-molecule reactions in the interface, the gas stream is selected slightly larger than the maximum the interface (input diaphragm) can allow through, which prevents drawing laboratory air with impurities and distortion of analytical information.;EFFECT: preventing blur of the optical window and contamination of the ionisation chamber and high sensitivity of the device.;1 dwg
机译:领域:物理学;物质:在大气压下具有光电离作用的离子源为空心氮气流的形式,该气流吹动毛细管色谱柱的加热出口,同时通过分离外部背景气体(实验室空气)用作电离室)来自色谱柱的载气流以及中空氮气流中的离子化物质。电离紫外线辐射源与气流正交放置。沿着气流轴形成的离子与气流一起被传输到分析仪接口的输入。为防止界面中发生二次离子分子反应,应选择略大于界面(输入隔膜)允许通过的最大气流的气体流,以防止吸入带有杂质的实验室空气和分析信息失真。光学窗口,电离室的污染以及设备的高灵敏度。; 1 dwg

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