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PREPARATION METHOD OF HYBRID THIN FILM SOLAR CELL AND HYBRID THIN FILM SOLAR CELL PREPARED THEREBY

机译:混合型薄膜太阳电池的制备方法及由此制备的混合型薄膜太阳电池

摘要

The present invention provides a preparation method comprising a step of forming a thin film of Cu_2ZnSn(S,Se)_4(CZTSSe) with a vacuum process on an upper part of a first electrode (a fist step); forming a thin film of porous Cu_2ZnSnS_4(CZTS) with a solvent process on an upper part of the thin film of Cu_2ZnSn(S,Se)_4(CZTSSe) formed in the first step (a second step); forming an n-type buffer layer on an upper part of the thin film of CZTS formed in the second step (a third step); and forming a second electrode on an upper part of the n-type buffer layer formed in the third step (a fourth step). A preparation method of a hybrid thin film solar cell according to the present invention has a superior effect in a conversion efficiency of photoelectricity for the prepared hybrid thin film solar cell, by forming an elaborate structured thin film of CZTSSe with a vacuum process, and forming porous thin film of Cu_2ZnSnS_4(CZTS) with a solvent process. Also, there is an effect that a performance of a solar cell can be more improved, in which a preparation is available with a non-vacuum process without using an organic material binder, when prepared a thin film of CZTS with a solvent process, and a morphology of a thin film, a size of a crystal grain and a control of porosity are readily available according to a temperature and a time of a preprocessing and a post processing of heat.;COPYRIGHT KIPO 2016
机译:本发明提供一种制备方法,其包括以下步骤:通过真空工艺在第一电极的上部上形成Cu_2ZnSn(S,Se)_4(CZTSSe)的薄膜(第一步骤);在第一步骤(第二步骤)中形成的Cu_2ZnSn(S,Se)_4(CZTSSe)的薄膜的上部通过溶剂处理形成多孔Cu_2ZnSnS_4(CZTS)的薄膜;在第二步骤(第三步骤)中形成的CZTS薄膜的上部上形成n型缓冲层;在第三步骤(第四步骤)中形成的n型缓冲层的上部上形成第二电极。根据本发明的混合薄膜太阳能电池的制备方法,通过用真空工艺形成精细的CZTSSe结构化薄膜并形成,从而在制备的混合薄膜太阳能电池的光电转换效率方面具有优异的效果。溶剂法制备Cu_2ZnSnS_4(CZTS)多孔薄膜。另外,具有这样的效果:当通过溶剂法制备CZTS薄膜时,其中不使用有机材料粘合剂就可以用非真空法进行制备,并且可以进一步提高太阳能电池的性能,以及根据热的预处理和后处理的温度和时间,可以轻松获得薄膜的形态,晶粒大小和孔隙率控制。; COPYRIGHT KIPO 2016

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