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S,S-DIOXO-DIBENZOTHIOPHENE UNIT-CONTAINING ELECTRON DONOR POLYMER AND USE THEREOF

机译:含S,S-二氧杂二苯并噻吩单元的电子主聚合物及其用途

摘要

Disclosed are a S,S-dioxo-dibenzothiophene unit-containing electron donor polymer and the use thereof. The main chain of the electron donor polymer contains a S,S-dioxo-dibenzothiophene unit. By a polymerization method, such as the Stille method, Suzuki method, etc., a novel D-A structure conjugated polymer is constructed. The S,S-dioxo-dibenzothiophene unit has good planarity and high electronegativity. The polymer is endowed with properties, such as a relatively deep HOMO energy level, strong intermolecular interaction, a high light-absorption coefficient, a high mobility and relatively high photoelectric response, so that the related polymer material has wide application prospects in organic solar cells or organic field effect transistor devices.
机译:公开了一种含S,S-二氧代-二苯并噻吩单元的电子供体聚合物及其用途。电子给体聚合物的主链包含S,S-二氧代-二苯并噻吩单元。通过Stille方法,Suzuki方法等聚合方法,构建了新型的D-A结构共轭聚合物。 S,S-二氧代-二苯并噻吩单元具有良好的平面性和高电负性。该聚合物具有较高的HOMO能级,较强的分子间相互作用,较高的光吸收系数,较高的迁移率和较高的光电响应等性能,因此相关的高分子材料在有机太阳能电池中具有广阔的应用前景。或有机场效应晶体管器件。

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