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Metalloporphyrin complex, manufacturing process therefor and carbon dioxide fixation catalyst therefrom, as well as process for manufacturing cyclic carbonate
Metalloporphyrin complex, manufacturing process therefor and carbon dioxide fixation catalyst therefrom, as well as process for manufacturing cyclic carbonate
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机译：金属卟啉配合物，其制备方法和由其制备的二氧化碳固定催化剂以及制备环状碳酸酯的方法
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摘要
There is provided a metalloporphyrin complex represented by general formula (1):; wherein M is a metal; A1 to A4 are independently of each other a substituent represented by general formula (2):-D-E+X− (2)wherein D is a divalent organic group having 1 to 20 carbon atoms; E+ is a quaternary ammonium group or quaternary phosphonium group having 3 to 60 carbon atoms; and X is a halogen atom. There is thus provided a metalloporphyrin complex which, when used as a carbon dioxide fixation catalyst, exhibits high catalytic activity, has a small environmental burden and can be easily synthesized.展开▼
机译：提供了由通式（1）表示的金属卟啉配合物： 其中M是金属; A 1 至A 4 彼此独立地是由通式（2）表示的取代基：<？in-line-formulae description =“在线表达式” end =“ lead”？>-DE + X − （2）<？in-line-公式description =“ In-line Formulae” end =“ tail”？> 其中D是具有1至20个碳原子的二价有机基团; E + 是具有3至60个碳原子的季铵基或季基; X是卤原子。因此，提供了一种金属卟啉配合物，当其用作二氧化碳固定催化剂时，具有高催化活性，环境负荷小并且易于合成。
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