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REAGENT SYSTEM AND METHOD FOR MODIFYING THE LUMINESCENCE OF LANTHANIDE (III) MACROCYCLIC COMPLEXES

机译:修饰镧系元素(III)大分子复合物发光度的试剂系统和方法

摘要

A spectrofluorimetrically detectable luminescent composition consists essentially of at least one energy transfer acceptor lanthanide(III) complex having an emission spectrum maximum in the range from 300 to 2000 nanometers and a luminescence-enhancing amount of at least one energy transfer donor selected from the group consisting of a fluorophore, a lumiphore, an organic compound, a salt of an organic ion, a metal ion, a metal ion complex, or a combination thereof. Such energy transfer donor enhances the luminescence of at least one energy transfer acceptor lanthanide(III) complex, with the conditions that the emission spectrum of any energy transfer donor differs from that of its energy transfer acceptor lanthanide(III) complex; and such energy transfer donor can be dissolved to form a unitary solution in a solvent having an evaporation rate at least as great as that of water.
机译:光谱荧光可检测的发光组合物基本上由至少一种能量转移接受体镧系元素(III)配合物组成,该配合物的最大发射光谱为300-2000纳米,并且发光增强量为至少一种选自以下组成的组的能量转移供体荧光团,荧光团,有机化合物,有机离子的盐,金属离子,金属离子络合物或它们的组合。这种能量转移供体增强了至少一种能量转移受体镧系元素(III)配合物的发光,条件是任何能量转移供体的发射光谱不同于其能量转移受体镧系元素(III)配合物的发射光谱。并且可以将这种能量传递供体溶解在蒸发速率至少与水一样大的溶剂中以形成单一溶液。

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