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CONTRACTION AND CONFINEMENT OF OIL SLICKS ON WATER, INCLUDING WATER WHERE ICE IS PRESENT, USING NON-IONIC SURFACTANTS

机译:使用非离子表面活性剂对包括水在内的滑油进行约束和约束

摘要

Methods for reducing the size of an oil slick on a water surface or on a water surface when ice is present are described. Spreading of oil can be reversed by reducing the surface tension of the seawater, for example, by using a low concentration of at least one water-soluble surfactant, such as a non-ionic surfactant. A controlled amount of the surfactant or surfactant mixture may be discharged over time at the inner-wall of a spill control boom surrounding the oil spill, or within the vicinity of the oil spill in the absence of control booms using a soaker hose or a floating polyethylene or polypropylene hose impregnated with surfactant, whereby the confinement and contraction of the oil slick is maintained by compensating for dissolved surfactant and surfactant moving away from the oil slick. Water-soluble surfactants are typically solids or gels at low temperatures when no organic co-solvent is added to the surfactant. The solid or gel form is advantageous for generating slow, but continuous release of surfactant, and thus there is no need for an organic co-solvent. This is not the situation for oil-soluble surfactants, which require an organic co-solvent to be successfully applied at low temperatures. Mixing oil-soluble surfactants with water-soluble surfactants may overcome the problem of dispersing oil-soluble surfactant without an organic co-solvent at low temperatures.
机译:描述了用于减小存在冰的情况下在水表面或水表面上的浮油的尺寸的方法。通过降低海水的表面张力,例如通过使用低浓度的至少一种水溶性表面活性剂,例如非离子表面活性剂,可以逆转油的扩散。随着时间的流逝,可以在围绕溢油的溢油控制吊臂的内壁或不使用溢油管或浮动装置的情况下,在没有控制吊臂的情况下,在受控溢油的围油壁内排放控制量的表面活性剂或表面活性剂混合物。浸渍有表面活性剂的聚乙烯或聚丙烯软管,从而通过补偿溶解的表面活性剂和从表面活性剂移走的表面活性剂来保持表面活性剂的约束和收缩。当没有有机助溶剂添加到表面活性剂中时,水溶性表面活性剂通常在低温下为固体或凝胶。固体或凝胶形式有利于产生缓慢但连续释放的表面活性剂,因此不需要有机助溶剂。对于油溶性表面活性剂来说不是这种情况,油溶性表面活性剂需要有机助溶剂才能在低温下成功应用。将油溶性表面活性剂与水溶性表面活性剂混合可以克服在低温下在没有有机助溶剂的情况下分散油溶性表面活性剂的问题。

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