首页> 外国专利> Modified conjugated diene (co) Method producing polymers, a method of manufacturing a modified conjugated diene (co) polymer containing rubber composition, and a pneumatic tire comprising a rubber composition produced by the production method

Modified conjugated diene (co) Method producing polymers, a method of manufacturing a modified conjugated diene (co) polymer containing rubber composition, and a pneumatic tire comprising a rubber composition produced by the production method

机译:改性共轭二烯(共)聚合物的制造方法,包含橡胶组合物的改性共轭二烯(共)聚合物的制造方法以及包含通过该制造方法制造的橡胶组合物的充气轮胎

摘要

The invention provides a method for producing a modified conjugated diene (co)polymer, the method including comprising: a modification reaction step including causing an organic silane compound to react with a conjugated diene (co)polymer having an active site at the active site, the organic silane compound having a characteristic group for forming a silanol group through hydrolysis and, in the vicinity of the characteristic group, (i) a functional group which binds the organic silane compound to the conjugated diene (co)polymer via addition to or substitution at the active site and which promotes reaction between the silanol group and a reinforcing filler after the addition or substitution reaction, or (ii) a functional group which promotes reaction between the silanol group and a reinforcing filler, and a hydrolyzation step performed after the modification reaction step; a modified conjugated diene (co)polymer having, at a molecular end of the conjugated diene (co)polymer, a silanol group, and a functional group in the vicinity of the silanol group, the functional group accelerating reaction between the silanol group and the reinforcing filler; a rubber composition containing the (co)polymer and carbon black having specific characteristics; and a tire formed from the rubber composition.
机译:本发明提供了一种生产改性共轭二烯(共)聚合物的方法,该方法包括:改性反应步骤,包括使有机硅烷化合物与在活性位点具有活性位的共轭二烯(共)聚合物反应,具有通过水解形成硅烷醇基的特征基团的有机硅烷化合物,以及在该特征基团附近的(i)通过加成或取代而将有机硅烷化合物与共轭二烯(共)聚合物结合的官能团在加成或取代反应后在活性位点处促进硅烷醇基与增强填料之间的反应,或(ii)促进硅烷醇基与增强填料之间的反应的官能团,以及在改性后进行的水解步骤反应步骤在共轭二烯(共)聚合物的分子末端具有硅烷醇基和在硅烷醇基附近的官能团的改性共轭二烯(共)聚合物,该官能团促进了硅烷醇基与硅烷之间的官能团反应。增强填料;含有(共)聚合物和具有特定特性的炭黑的橡胶组合物;以及由橡胶组合物形成的轮胎。

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