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SYNTHESIS OF PDMS-BASED POLYROTAXANE, PURIFIED PDMS-BASED POLYROTAXANE AND PDMS-BASED POLYROTAXANE DERIVATIVES

机译:基于PDMS的聚环氧乙烷,纯PDMS的聚环氧乙烷和基于PDMS的聚环氧乙烷衍生物的合成

摘要

The present invention provides a new synthetic process of PDMS (polydimethylsiloxane)-based polyrotaxane, which comprises a step of reacting pseudopolyrotaxane consisting of PDMS and CDs (cyclodextrins) with an end-capping agent, by (a) a radical coupling reaction, or (b) a microwave coupling reaction. By the method of the present invention, PDMS-based polyrotaxane can be obtained with high filling ratio of CDs on the PDMS chain.
机译:本发明提供了一种新的基于PDMS(聚二甲基硅氧烷)的聚轮烷的合成方法,该方法包括以下步骤:通过(a)自由基偶联反应,或(P) b)微波偶联反应。通过本发明的方法,可以以高的CD在PDMS链上的填充率获得基于PDMS的聚轮烷。

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