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SYNTHESIS OF PDMS-BASED POLYROTAXANE, PURIFIED PDMS-BASED POLYROTAXANE AND PDMS-BASED POLYROTAXANE DERIVATIVES
SYNTHESIS OF PDMS-BASED POLYROTAXANE, PURIFIED PDMS-BASED POLYROTAXANE AND PDMS-BASED POLYROTAXANE DERIVATIVES
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机译:基于PDMS的聚环氧乙烷,纯PDMS的聚环氧乙烷和基于PDMS的聚环氧乙烷衍生物的合成
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摘要
The present invention provides a new synthetic process of PDMS (polydimethylsiloxane)-based polyrotaxane, which comprises a step of reacting pseudopolyrotaxane consisting of PDMS and CDs (cyclodextrins) with an end-capping agent, by (a) a radical coupling reaction, or (b) a microwave coupling reaction. By the method of the present invention, PDMS-based polyrotaxane can be obtained with high filling ratio of CDs on the PDMS chain.
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