首页>
外国专利>
Method for producing crystalline coordination compound of diisothiocyano(bis(3,5-dimethylpyrazol-1-yl)methylamine) cobalt(II)
Method for producing crystalline coordination compound of diisothiocyano(bis(3,5-dimethylpyrazol-1-yl)methylamine) cobalt(II)
展开▼
机译:[二异硫氰基(双(3,5-二甲基吡唑-1-基)甲胺)钴(II)]的晶体配位化合物的制备方法
展开▼
页面导航
摘要
著录项
相似文献
摘要
the invention relates to crystalline forms of means of production in situ unknown yet complex: [diizotiocyjano (bis (3,5 - dimetylopirazol - 1 - yl) metyloaminakobalt (ii)] (model 1) [what (luls) 2l), where l is the bis (3,5dimetylopirazol - 1 - yl) methylamine.the complex was formed by mixing the reagent such as metallic cobalt, 1 - hydroxy - 3,5 - dimetylopirazol, nh4scn, in the presence of moo3, combined in a mole ratio of 2: 4: 6: 1. both complex and an organic ligand bis (3,5 - dimetylopirazol - 1 - yl) methylamine (l) and (ii) ions are formed in situ during synthesis.relationship piu0119ciokoordynacyjne contains ions that (ii), combined with the resulting in the synthesis of organic ligandem (l) (model 5), by three donor atoms of nitrogen and two receptor luls - coordination, also by nitrogen. do not dissolve in water, slightly soluble in methanol and ethanol, very well soluble in ch3cn and ch2cl2.in the air is stable thermally to temperature 130u00b0c shows photoluminescent properties.
展开▼