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To produce a fuel having an organic sulfur compound of the ultra-low levels, mild hydrodesulfurization of integrated gas-phase catalytic oxidation

机译:为了生产具有超低含量有机硫化合物的燃料,需要进行整体气相催化氧化的轻度加氢脱硫

摘要

In the hydrodesulfurization reaction zone operated under mild conditions to remove unstable organic sulfur compounds, desulfurization of the hydrocarbon feedstock is first achieved by contacting the hydrodesulfurization catalyst with the entire feedstock. . To obtain two hydrocarbon fuel fractions, the flushing column downstream of the hydrodesulfurization reaction zone fractionates the effluent at the target cut point temperature. The first fraction boiling at or above the target cut point temperature contains residual refractory organosulfur compounds. Since the organosulfur compounds boiling in this fraction range were unstable organosulfur compounds that were first removed by mild hydrodesulfurization, the second fraction boiling below the target cut-point temperature is essentially Organic sulfur compounds are not included. Contacting the first fraction with a gaseous oxidant over an oxidation catalyst having the formula CuxZn1-xAl2O4 in a gas phase catalytic oxidation reaction zone to convert refractory organic sulfur compounds to SOx and low sulfur hydrocarbons Let Byproduct SOx is then removed to produce a stream containing reduced levels of organosulfur compounds. [Selection] Figure 2
机译:在温和条件下操作以除去不稳定的有机硫化合物的加氢脱硫反应区中,首先通过使加氢脱硫催化剂与整个原料接触来实现烃原料的脱硫。 。为了获得两个烃类燃料馏分,加氢脱硫反应区下游的冲洗塔在目标切割点温度下对流出物进行分馏。沸点等于或高于目标切点温度的第一馏分包含残留的难熔有机硫化合物。由于在该馏分范围内沸腾的有机硫化合物是不稳定的有机硫化合物,它们首先通过温和的加氢脱硫而被除去,因此沸点低于目标临界温度的第二馏分基本上不包括有机硫化合物。在气相催化氧化反应区中,将第一馏分与气态氧化剂在通式为CuxZn1-xAl2O4的氧化催化剂上接触,将难处理的有机硫化合物转化为SOx和低硫烃,然后将副产物SOx除去,生成含有机硫化合物的含量。 [选择]图2

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