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PROCESS FOR THE SYNTHESIS OF PHTHALOCYANINE COMPLEXES OF ZIRCONIUM AND HAFNIUM WITH OUT-OF-PLANE KETOESTERATE LIGANDS

机译:平面外酯酸酯配体合成锆和HA的酞菁配合物的方法

摘要

A process for the synthesis of bis(-ketoesterato)phthalocyanine of zirconium (IV) and hafnium (IV) by interaction of zirconium or hafnium dichloride-(oxo- or dihydroxo-)phthalocyanine with -ketoesters in ratio of phthalocyanine: -ketoester as 1:2 to 1:4 while heating in water from 25 to 100°C for 2 to 24 hours optionally in the presence of organic or inorganic base.
机译:一种通过二氯化锆或ha-酞菁与-酮酸酯的比例为酞菁:-酮酸酯的比例合成锆(IV)和ha(IV)的双(酮酸酯)酞菁的方法:2:1:4,同时在有机或无机碱的存在下在25至100°C的水中加热2至24小时。

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