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TAPERED TRIBLOCK COPOLYMERS.

机译:锥型三嵌段共聚物。

摘要

A tapered triblock copolymer having controlled vinyl distribution, enlarged middle block with intermediate composition and microstructure, increased compatibility between its adjacent blocks, good processing characteristics and a peak average molecular weight between 25,000 and 300,000 is made by anionically polymerizing conjugated diene and monovinyl aromatic monomers, polar modifier and initiator to make a first block rich in conjugated diene, forming a second block that is a copolymer of the conjugated diene and the monovinyl aromatic monomer and which is less rich in the conjugated diene than the first block, and forming a third block that is a homopolymer of the monovinyl aromatic monomer. The first, second and third blocks comprise 30 to 60, 20 to 50wt % and 10 to 40 wt % of the tapered triblock copolymer, respectively. The tapered triblock copolymers may be used as asphalt modifiers, adhesives, sealants, compatibilizers, reinforcing agents and impact modifiers.
机译:通过对共轭二烯和单乙烯基芳族单体进行阴离子聚合,制得一种具有受控乙烯基分布,中间结构和微观结构扩大的中间嵌段,相邻嵌段之间相容性提高,中间工艺特性好,峰均分子量在25,000至300,000之间的峰均三嵌段共聚物,极性改性剂和引发剂,以使第一嵌段富含共轭二烯,形成第二嵌段,该第二嵌段是共轭二烯与单乙烯基芳族单体的共聚物,并且与第一嵌段相比,其共轭二烯的含量少,并形成第三嵌段即单乙烯基芳族单体的均聚物。第一,第二和第三嵌段分别占锥形三嵌段共聚物的30至60、20至50wt%和10至40wt%。锥形三嵌段共聚物可以用作沥青改性剂,粘合剂,密封剂,增容剂,增强剂和抗冲改性剂。

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