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Process for producing a directionally solidified material body, in particular a metal or semimetal body, and uses thereof

机译:定向凝固的材料体,特别是金属或半金属体的制造方法及其用途

摘要

The invention relates to a method for producing a directionally solidified material body, in particular a mono- or quasi-monocrystalline metal or semi-metal body, by directional solidification from a melt, a crucible (1) being prepared by the bottom of which is provided with a plurality of thin monocrystalline seed crystal plates ( 2a-2d) is covered with a predetermined orientation of its crystal axes in order to form a seed crystal plate layer, and in the crucible (1) thus prepared, a melt is solidified in the direction of the material body (ingot) under the influence of a temperature gradient prevailing in a vertical direction. According to the invention, one of the crystal axes of the seed crystal plates (2a-2d) is tilted relative to the vertical direction (z) by a predetermined acute tilt angle (α) and immediately adjacent seed crystal plates are differently oriented. The deviation of the surface of the crystal from the ideal (001) direction is negligible according to the invention, so that efficient solar cells can be formed in particular by means of an alkaline texture. It has been observed in particular that any dislocation clusters in the material block do not correlate with the arrangement of the joints of the seed crystal plates originally laid out on the crucible bottom and cannot spread further into the material body.
机译:本发明涉及一种用于通过从熔体中进行定向凝固来制备定向凝固的材料体,特别是单或准单晶金属或半金属体的方法,其中,坩埚(1)的底部是设置有多个薄的单晶晶种板(2a-2d),以其晶轴的预定方向覆盖以形成晶种板层,并且在如此制备的坩埚(1)中,将熔体凝固成在垂直方向上普遍存在的温度梯度的影响下,材料主体(锭子)的方向。根据本发明,籽晶板(2a-2d)的晶轴之一相对于垂直方向(z)倾斜预定的锐角(α),并且紧邻的籽晶板的取向不同。根据本发明,晶体的表面从理想的(001)方向的偏离可以忽略不计,从而特别是可以通过碱性纹理形成有效的太阳能电池。特别地,已经观察到,材料块中的任何位错簇与最初布置在坩埚底部上的籽晶板的接头的布置不相关,并且不能进一步扩散到材料主体中。

著录项

  • 公开/公告号DE102012102597A1

    专利类型

  • 公开/公告日2013-09-26

    原文格式PDF

  • 申请/专利权人 SCHOTT SOLAR AG;

    申请/专利号DE102012102597A1

  • 发明设计人 BERNHARD BIRKMANN;FRIEDER KROPFGANS;

    申请日2012-03-26

  • 分类号C30B11/14;C30B28/06;C30B35;H01L31/18;C30B11/02;

  • 国家 DE

  • 入库时间 2022-08-21 16:21:51

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